AOSC 434/658R & CHEM 434/678A Air Pollution

Instructors: Ross Salawitch and Tim Canty

Tues-Thurs, 2:00 to 3:15 pm, CSS 2416

Spring 2011: 3 units

Required Text:

            Chemistry in Context: Applying Chemistry to Society

                        6th edition, American Chemical Society

 

  

Supplemental Text:

 

            Global Warming: The Complete Briefing (third edition) by John Houghton

 

The Atmospheric Environment by Michael B. McElroy

 

Beyond Oil and Gas: The Methanol Economy by George A. Olah, Alain Goeppert, and G. K. Surya Prakash

 

Atmospheric Pollution by Mark Z. Jacobson

 

Note: readings will be assigned from each supplemental text.  Electronic versions of these readings will be provided in password protected files.

 

1. Course Description

2. Course Schedule

3. Grade Policy

4. Admission Tickets

5. Additional Readings

6. Collaboration Policy

7. Office Hours

1. Course Description

This class focuses on air pollution as it relates to atmospheric chemistry and climate change. We cover global warming, air quality (smog, particulates, heavy metals), and stratospheric ozone depletion, focusing on the role of long lived, well mixed greenhouse gases as well as shorter-lived pollutants, most of which affect both atmospheric ozone and the radiative forcing of Earth’s climate.  We teach fundamentals of atmospheric chemistry (spectroscopy, radiative transfer, kinetics, isotopic analysis, and global biogeochemical cycles) and apply these fundamentals to the modern understanding of air quality, ozone depletion, and climate change, using resources such as contemporary satellite observations, recent field campaigns, and “assessments” compiled by international scientific teams.  We conclude the course with a series of lectures focused on how society might meet future energy needs of society in a manner that is both economically viable and ecologically sound.  The course is taught at a level appropriate for upper class undergraduate physical science majors and first year graduate students.

Pre-requisites: CHEM 131 and MATH 241 or their equivalents (i.e., CHEM 271 or CHEM 276 or advanced physics courses can substitute for MATH 241) or the permission of the instructors.

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2. Schedule

Date

Lecture Topic

Lecturer

Required Readings

Admis. Tickets

Lecture Notes

Problem Sets*

Additional Readings

01/25

Geological Evolution of Earth's Atmosphere

RJS

 

 

Lecture 1

 

Sci American CH4 Mars & Titan May 2007

01/27

           

02/01

Overview of Global Warming, Air Quality, & Ozone Depletion

RJS

IPCC 2007 FAQ

(questions 1.1, 1.2, 1.3, 2.1, & 3.1)

EPA AQI Brochure

(entire document; only 10 pgs J)

WMO 2006 20 QAs

(questions 1, 2, 3, 10, 15 & 18)

Click here for entire WMO 2006 20 QAs

Click here for entire IPCC 2007 FAQ

AT 2

Lecture 2  

 

.

Chemistry in Context, Ch 2 (pg 57 to 72)

Sci American Why is there an ozone hole?  Aug 2007

Kerr, Science, 2007

 

Bell et al., EHP, 2006

 

02/03

Fundamentals of Earth’s Atmosphere

TC

Chemistry in Context, Sections 1.1, 1.2, and 1.5

Jacobson,

pg 50-64

AT 3

Lecture 3

 

 Houghton, Ch 2

02/08

Climates of the Past

RJS

Chemistry in Context, pgs 100-110

 

Houghton, Ch 4

(pgs 64-71)

IPCC 2007 FAQ

(questions 6.1, 6.2)

AT 4

Lecture 4

 

Chylek & Lohmann, GRL, 2008

Hewitt & Mitchell, Clim. Dyn., 1997.

02/10

Global Carbon Cycle

RJS

Chemistry in Context, Ch 3 (pg 118-126)

Houghton, Pg 29-42

Note: above links contain reading material for Lectures 5 & 6

 AT 5

Lecture 5

 

IPCC 2007, Section 7.3.4.1 & Box 7.3

 

Sci American Ocean Acidification

March 2006

02/15

Biogeochemical Cycles of CH4 and N2O

RJS

Chemistry in Context, Ch 3 (pg 126-129)

Houghton, Pg 42-44

Note: above links point to same material used for Lecture 5

Jacobson,

Pg 45-47 &

Pg 70-71

  AT 6

Lecture 6

Problem Set 1  due today

Revised 14 Feb

Sci American CH4 From Plants

Feb 2007 (hypothesis)

 

New Phytologist CH4 From Plants

July 2007

(refutation)

02/17

Radiative Forcing

TC

Chemistry in Context, Ch 3 (pg 110-118)

 AT 7

Lecture 7

 

Myhre et al., GRL, 1998

Bera et al., JPC,   2009

02/22

Modeling Earth’s Climate: Cloud, Aerosol, & Water Vapor Feedbacks

TC

Houghton, pg 88-95

Jacobson,

Pg 337 to 341

 AT 8

Lecture 8

Problem Set 2  due today

Su et al., GRL, 2006

 

Houghton, Ch 5 (in its entirety)

02/23 Review Discussion for First Exam

The same review will be held twice:

   Session I : 6:30 to 7:30 pm

   Session II: 9:30 to 10:30 pm

Review will be in regular class room.

RJS & TC     Review A    
02/24 First Exam: Focus on first 8 lectures and first 2 problem sets (in class, closed book)            
03/01 Review of First Exam

and

Introduction to Atmospheric Chemistry

RJS

No reading J

Student Survey:

Word

PDF

Lecture 9    

03/03

Introduction to Photolysis

RJS

Section 2.4 of Warneck, Chemistry of the Natural Atmosphere

None

 

Lecture10

 

Brasseur and Solomon, pages 40 to 48 (section 2.6), pages 218 and 219 section 4.7.1), and pages 246 and 247 (section 4.7.3)

03/08

Introduction to Chemical Kinetics

RJS

Yung & DeMore,  Ch 3

AT 11

Lecture11

 

Bimolecular Rate Constant Table, JPL 2006

Brasseur & Solomon, pgs 12 to 40

03/10

Pollution of Earth’s Troposphere:

   Surface Ozone

RJS

Chemistry in Context, Ch 1

(focus on Sections 1.3, 1.4, 1.9, 1.10, 1.11, and 1.12)

AT 12

Lecture12

 

 

03/15

Pollution of Earth’s Troposphere:

   Acid Rain & Aerosols

TC

Chemistry in Context, (pg 246 to 270)

Jacobson (pg 118 to 128)

AT 13 Lecture13    
03/17

Review of Lectures 9 through 13

RJS      

 Problem Set 3 due today

Revised 6 Mar

Tropospheric Ozone from Space

Spring Break: enjoy !

03/29

Pollution of Earth’s Stratosphere:

   Mid-Latitude Ozone Depletion

RJS

McElroy, Chapter 13

(pgs 175-178 & 183-187)

 

McElroy,

Chapter 14

AT 15

Lecture15

 

WMO 2006 20 QAs

(quest.13-17)

03/31

Pollution of Earth’s Stratosphere:

   Polar Ozone Depletion

RJS

Chemistry in Context, Ch 2 (pg 79 to 94)

 

AT 16

Lecture16

 

WMO 2006 20 QAs

(quest. 9-12)

 

  McElroy,

  Chapter 15

04/05

Pollution of Earth’s Stratosphere:

   Ozone Recovery and Chemistry/Climate   

   Interactions

RJS

WMO 2006 20 QAs

(quest. 19 & 20)

 

 

AT 17

Lecture17

 

Yang et al. 2008

Yang et al. 2006

Randenyi et al. 2002

04/07 Review Discussion for Second Exam

Note: if we have a second snow day, this review will be moved to the evening of 04/11.

RJS & TC     Review B Problem Set 4 due today

Revised 5 Apr

 

04/12

Second Exam: Focus on lectures 9 to 17 and problem sets 3 and 4 (in class, closed book ... please bring a calculator)

 

 

 

 

   

04/14

Fossil Fuel Reserves, The Kyoto Protocol and the Science of CO2 Stabilization

RJS

Chemistry in Context, Section 3.10 to 3.12 (pgs 134-143)

IPCC 2007 FAQ (question 10.3)

AT 18

Lecture18

.

Houghton, Ch 10

04/19

Review of Second Exam and

World Energy Needs, Fossil Fuel Reserves (cont'd), and CO2 Sequestration

RJS

Houghton,

pgs 268-288

Peak Oil Wikipedia

AT 19

Lecture19

 

Chemistry in Context, Section 4.3 to 4.7

Raupach et al. 2007

04/21 Impacts of Climate Change TC Houghton, pgs 145- 155

Shepherd and Wingham, 2007

AT 20

Lecture20

 

Section 3, IPCC 2007 Synthesis Report

04/26

Renewable Energy I: Solar, Geothermal, Hydro, & Wind

RJS

Chemistry in Context,

Section 8.9 and 8.10

(pgs 353-362)

Olah, pgs 84-101

AT 21

Lecture21

 

 

04/28

Renewable Energy II: Biofuels, Ethanol, Methanol, and Algae

RJS

Chemistry in Context, Ch 4, Section 4.10

(pg 178-183)

 

McElroy, The Ethanol Illusion

AT 22  

Lecture22

Problem Set 5 due today

Olah, various pages on Biofuels and Methanol

 

Wigmosta et al., WRR, 2011

05/03

Nuclear Energy & The Hydrogen Economy

TC

Chemistry in Context, Sections 7.3, 7.4, 7.6, and 7.8 to 7.10

Olah, Ch 8, pages 111-119 (bottom)

Olah, Ch 9, pages 140-154 (top)

 

AT 23

Lecture23  

Chemistry in Context,

rest of Ch 7

 

Olah, rest of Ch 8

 

Olah, rest of Ch 9

05/05 Geo-engineering of Climate RJS

Crutzen GeoEng Essay

IEEE GeoEng Overview

GeoTimes GeoEng Debate

AT 24

Lecture24

Problem Set 6 due today

Assigned only to Undergrad Students

Tilmes et al., 2008

Mon

05/09

Evening Review: Preparation for Final Exam

and

Presentation of Selected Problem Set #6 Solutions (Undergrads)

    Regular classroom (CSS 2416)

     6:00 to 7:00 pm

  

RJS & TC     Review C

Video of final lecture

 

 

05/10

Student Research Projects (Graduate Students)

Graduate

Students

 

 

 

Grad Student paper due

 

Mon

05/16

Final Exam

CSS 2416: 10:30 am to 12:30 pm

           

*  Problem sets are due on the date listed 

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3. Grade Policy

The final grades will be based on problems sets (30%), admission tickets (10%), in-class exams (40%), and final exam (20%).  In addition, graduate students are required to write a research paper (8 pages single spaced) on a topic of their choosing related to the material covered in class.  Graduate students will make a brief oral presentation of their research paper during the last meeting.  For graduate students, the grade on the paper/presentation will be factored into their overall grade at a proportion equal to the weight of each exam.  Also, graduate students will have an occasional extra question on problem sets.

 

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4. Admission Tickets

To encourage completion of the reading assignments prior to class, there is an admission ticket due at the start of each class (with the exception of the first lecture). The admission ticket is a short question (or set of questions) drawn from the readings.  Each ticket will be graded in a prompt manner and typically returned at the start of the next class.  The lowest three scores will be dropped, and a final overall admission ticket grade will be determined, based on overall  percentage of available points achieved. This allows for uniform grading of admission tickets with a variety of assigned points.  The overall admission ticket grade counts 10% towards the final course grade.

In many cases, the answer(s) to the admission ticket question(s) will be worked into the lecture.    Hence, the requirement that admission ticket solutions be turned in at the start of lecture! If you can not make a lecture, you are welcome to email us your solution prior to class or have a classmate turn in your solution.  Late submissions of admission ticket solutions are generally not accepted.  Since the three lowest scores are dropped and  admission tickets constitute only 10% of the overall grade, we are rather strict about not accepting late solutions.  Again, these questions are designed to motivate completion of the assigned reading prior to lecture, which we feel is an important component of learning the material.

Admission tickets will be posted on this website at least 24 hours prior to the start of each lectureIf an admission ticket for a particular lecture is not posted by 2 pm the day prior to a particular lecture, there will be no admission ticket for that class.  Also, if an item other than an admission ticket link appears in the admission ticket column for a particular lecture (i.e., lectures 1, 9, and 13), there will no admission ticket for that class meeting.

We may administer an occasional, in class “pop quiz”.  This will be done if it is apparent that a majority of students are not completing the readings prior to class (i.e., if the admission ticket answers seem, in aggregate, to be based on Google searches of key phrases rather than reading of the assigned material).  If one or more “pop quiz” is given, the results will be factored into the “admission ticket” portion of the grade.

Please remember to hit the “refresh” button to see the latest version of this website each time you visit, as we intend to update the website file frequently during the course (if the symbol × is changed to the symbol P, this may not be apparent unless the page is refreshed).

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5. Additional Readings

Additional readings are provided for many lectures.  This material is provided to allow interested students to read further about a particular topic.  The material in these additional readings will not form the sole basis of any exam question, nor will this material be of purposeful advantage for the successful completion of the problem sets.  The course will be enhanced for those with time to explore the additional readings.

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6. Collaboration Policy

For completion of the Admission Tickets and Problem Sets, you may consult any text or website you desire.  While we encourage reliance on the assigned reading and discourage use of search engines for the completion of the Admission Tickets, we also understand the utility of search engines and understand they could provide a useful resource on occasion. Regardless, the material you turn in for Admission Tickets and Problem Sets should reflect your understanding of the material and only your work.  We encourage discussion among classmates of general course concepts, but specific details of how to solve particular admission ticket questions and/or problem set questions should not be shared with classmates prior to the assignment being submitted.  After problem sets and/or exams have been returned, you are welcome to discuss the material, including details of solutions, with other students.  Also, it is fine to prepare for the examinations by discussing class material with other students.  We take care to change questions from year to year, in part to keep the material fresh but also to discourage reliance on "files" passed down from prior students.

In other words ... it is not permissible to copy solutions for Admission Tickets and Problem Sets from other students or from "files" for this class maintained by prior students.  Indeed, we strongly discourage the maintenance of "files" for this class and we assure everyone that exam questions used this semester will not be a repeat of questions from prior exams.

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7. Office Hours

Office Hours:   Monday, 2:30 to 3:30 pm  & by appointment

After class often works although the AOSC seminar is Thurs at 3:30 pm (i.e., Tues after class is better than Thurs after class); prior to class is not preferred because we are typically focused on preparing for the lecture.

Office Location: Ross Salawitch       CSS (bldg 224), room 2403  phone: 5-5396

                            Tim Canty                 CSS (bldg 224), room 2411  phone: 5-5360

 

W strive for one of us to be in our office (just down the hall from each other) every Monday, between 2:30 and 3:30 pm.  Please contact us via phone or email if an appointment is desired.

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Website last updated on Tuesday, 10 May 2011