LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 01 of 05
Removable Threadlocker 242
24221
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name: Removable Threadlocker 242
Item No.: 24221 Part of Kit: 00101
Product Type: Anaerobic
2. COMPOSITION, INFORMATION ON INGREDIENTS
Ingredients CAS No. %
Polyglycol dimethacrylate 25852-47-5 60-65
Polyglycol oleate 9004-96-0 25-30
SACCHARIN 81-07-2 3-5
CUMENE HYDROPEROXIDE* 80-15-9 1-3
Propylene glycol 57-55-6 1-3
SILICA, AMORPHOUS, FUMED,
CRYSTALLINE-FREE 112945-52-5 1-3
N,N-Dialkyltoluidines 613-48-9 0.1-1
TITANIUM DIOXIDE 13463-67-7 0.1-0.5
* This component is listed as a SARA Section 313 Toxic Chemical.
Ingredients which have exposure limits
Exposure Limits (TWA) ACGIH OSHA OTHER
Ingredients (TLV) (PEL)
SILICA, AMORPHOUS, FUMED,
CRYSTALLINE-FREE 10 mg/m3 TWA 6 mg/m3 TWA 3 mg/m3 TWA
resp. dust
TITANIUM DIOXIDE 10 mg/m3 dust 15 mg/m3 dust None
5 mg/m3 resp
Exposure Limits (STEL) ACGIH OSHA
Ingredients (TLV) (PEL)
3. HAZARDS IDENTIFICATION
Toxicity: Mild eye irritant. Propylene glycol is a mild
skin irritant.
Primary Routes of Entry: Eye, skin contact.
Signs and symptoms
of Exposure: May cause dermatitis on prolonged contact in
sensitive individuals
Existing Conditions
Aggravated by Exposure: Propylene glycol: dermatitis
LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 02 of 05
Product Name: Removable Threadlocker 242
Item No.: 24221
3. HAZARDS IDENTIFICATION (continued)
Literature Referenced Carcinogen
Ingredients Target Organ and Other Health Effects NTP IARC OSHA
Polyglycol dimethacrylate ALG IRR NO NO NO
Polyglycol oleate IRR NO NO NO
SACCHARIN No Data YES 2B NO
CUMENE HYDROPEROXIDE ALG CNS COR IRR MUT NO NO NO
Propylene glycol IRR NO NO NO
SILICA, AMORPHOUS, FUMED,
CRYSTALLINE-FREE NUI NO N/A NO
N,N-Dialkyltoluidines No Data NO NO NO
TITANIUM DIOXIDE AC4 IRR NUI NO NO NO
-------------------------------------------------------------------------------
Abbreviations
N/A Not Applicable 2B Possibly carcinogenic to humans
AC4 ACGIH-Unclassifiable as human carc. ALG Allergen
CNS Central nervous system COR Corrosive
IRR Irritant MUT Mutagen
NUI Nuisance dust
4. FIRST AID MEASURES
Ingestion: Do not induce vomiting. Keep individual calm.
Obtain medical attention
Inhalation: Does not apply
Skin Contact: Wash thoroughly with soap and water
Eye Contact: Flush at least 15 minutes with water. Obtain
medical attention.
5. FIRE FIGHTING MEASURES
Flash Point: More than 200°F Method: Tag Closed Cup
Recommended
Extinguishing Agents: Carbon dioxide, foam, dry chemical
Hazardous Products formed
by Fire or Thermal Decomp Irritating organic vapors; oxides of carbon.
Unusual Fire or
Explosion Hazards: None
Explosive Limits:
(% by volume in air)Lower Propylene glycol: 2.6%
(% by volume in air)Upper Propylene glycol: 12.5%
LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 03 of 05
Product Name: Removable Threadlocker 242
Item No.: 24221
6. ACCIDENTAL RELEASE MEASURES
Steps to be taken in case
of spill or leak: Soak up in an inert absorbant. Store in a partly
filled, closed container until disposal.
7. HANDLING AND STORAGE
Safe Storage: Store below 100°F
(Contact Loctite Customer Service 1-800-243-4874 for shelf Life information)
Handling: Avoid prolonged skin contact. Keep away from eyes.
8. EXPOSURE CONTROLS, PERSONAL PROTECTION
Eyes: Safety glasses or goggles.
Skin: Neoprene, rubber, or butyl rubber gloves.
Ventilation: Does not apply
See Section 2 for Exposure Limits.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Blue liquid
Odor: Mild
Boiling Point: More than 300°F
pH: Does not apply
Solubility in Water: Slight
Specific Gravity 1.1 at 75°F
Volatile Organic Compound
(EPA Method 24) 13.3%; 146 grams per liter
Vapor Pressure: Less than 5mm at 80°F
Vapor Density: Not available
Evaporation Rate
(Ether = 1) Not available
10. STABILITY AND REACTIVITY
Stability: Stable
Hazardous Polymerization: Will not occur
Incompatibility: Strong oxidizers, free radical initiators, inert
gases.
Conditions to Avoid: Not available
Hazardous Decomposition
Products (non-thermal): None
11. TOXICOLOGICAL INFORMATION
Oral LD50 more than 10000 mg/kg.
Dermal LD50 more than 5000 mg.kg.
LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 04 of 05
Product Name: Removable Threadlocker 242
Item No.: 24221
12. ECOLOGICAL INFORMATION
No data available
13. DISPOSAL CONSIDERATIONS
Recommended methods of
disposal: Incinerate following EPA and local regulations.
EPA Hazardous Waste
Number NH - Not a RCRA Hazardous Waste Material
14. TRANSPORTATION INFORMATION
DOT (49 CFR 172)
Domestic Ground Transport
Proper Shipping Name: Unrestricted
Hazard Class or
Division: Unrestricted
Identification Number: None
Marine Pollutant: None
IATA
Proper Shipping Name: Unrestricted
Class or Division: Unrestricted
UN or ID Number: None
15. REGULATORY INFORMATION
CA Proposition 65: This product contains Saccharin. No prop65 hazard
warning is necessary if this product is used as
reasonably anticipated.
16. OTHER INFORMATION
Estimated NFPA(R) Code:
Health Hazard: 1
Fire Hazard: 1
Reactivity Hazard: 1
Specific Hazard: Does not apply
Estimated HMIS(R) Code:
Health Hazard: 1*
Flammability Hazard: 1
Reactivity Hazards: 1
Personal Protection: See Section 8.
NFPA is a registered trademark of the National Fire Protection Assn.
HMIS is a registered trademark of the National Paint and Coatings Assn.
Prepared By: Stephen Repetto
Title: Research Chemist, Health and Safety
LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 05 of 05
Product Name: Removable Threadlocker 242
Item No.: 24221
16. OTHER INFORMATION (continued)
Company: Loctite Corporation
1001 Trout Brook Crossing, Rocky HIll CT 06067
(24hr.) Phone: (860) 571-5100
Revision Date: April 15, 1997 Revision: 0031
LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 01 of 05
Permanent Threadlocker 262
26221
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name: Permanent Threadlocker 262
Item No.: 26221 Part of Kit: 00101
Product Type: Anaerobic
2. COMPOSITION, INFORMATION ON INGREDIENTS
Ingredients CAS No. %
Polyglycol dimethacrylate 25852-47-5 65-70
Bisphenol A fumarate resin 39382-25-7 20-25
CUMENE HYDROPEROXIDE* 80-15-9 1-3
Poly(ethylene) 9002-88-4 1-3
SACCHARIN 81-07-2 1-3
N,N-Dialkyltoluidines 613-48-9 0.1-1
SILICA, AMORPHOUS, FUMED,
CRYSTALLINE-FREE 112945-52-5 0.1-1
* This component is listed as a SARA Section 313 Toxic Chemical.
Ingredients which have exposure limits
Exposure Limits (TWA) ACGIH OSHA OTHER
Ingredients (TLV) (PEL)
SILICA, AMORPHOUS, FUMED,
CRYSTALLINE-FREE 10 mg/m3 TWA 6 mg/m3 TWA 3 mg/m3 TWA
resp. dust
Exposure Limits (STEL) ACGIH OSHA
Ingredients (TLV) (PEL)
3. HAZARDS IDENTIFICATION
Toxicity: Mild eye irritant.
Oral LD50 more than 10,000 mg/kg.
Dermal LD50 more than 5000 mg/kg.
Primary Routes of Entry: Eyes, skin
Signs and symptoms
of Exposure: May cause dermatitis on prolonged contact in
sensitive individuals
Existing Conditions
Aggravated by Exposure: None known
LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 02 of 05
Product Name: Permanent Threadlocker 262
Item No.: 26221
3. HAZARDS IDENTIFICATION (continued)
Literature Referenced Carcinogen
Ingredients Target Organ and Other Health Effects NTP IARC OSHA
Polyglycol dimethacrylate ALG IRR NO NO NO
Bisphenol A fumarate resin ALG IRR NO NO NO
CUMENE HYDROPEROXIDE ALG CNS COR IRR MUT NO NO NO
Poly(ethylene) No Data NO N/A NO
SACCHARIN No Data YES 2B NO
N,N-Dialkyltoluidines No Data NO NO NO
SILICA, AMORPHOUS, FUMED,
CRYSTALLINE-FREE NUI NO N/A NO
-------------------------------------------------------------------------------
Abbreviations
N/A Not Applicable 2B Possibly carcinogenic to humans
ALG Allergen CNS Central nervous system
COR Corrosive IRR Irritant
MUT Mutagen NUI Nuisance dust
4. FIRST AID MEASURES
Ingestion: Do not induce vomiting. Keep individual calm.
Obtain medical attention
Inhalation: Does not apply
Skin Contact: Wash thoroughly with soap and water
Eye Contact: Flush at least 15 minutes with water. Obtain
medical attention.
5. FIRE FIGHTING MEASURES
Flash Point: More than 200°F Method: Tag Closed Cup
Recommended
Extinguishing Agents: Carbon dioxide, foam, dry chemical
Hazardous Products formed
by Fire or Thermal Decomp Irritating organic vapors
Unusual Fire or
Explosion Hazards: None
Explosive Limits:
(% by volume in air)Lower Not available
(% by volume in air)Upper Not available
LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 03 of 05
Product Name: Permanent Threadlocker 262
Item No.: 26221
6. ACCIDENTAL RELEASE MEASURES
Steps to be taken in case
of spill or leak: Soak up in an inert absorbent. Store in a partly
filled, closed container until disposal.
7. HANDLING AND STORAGE
Safe Storage: Store below 100°F
(Contact Loctite Customer Service 1-800-243-4874 for shelf Life information)
Handling: Avoid prolonged skin contact. Keep away from eyes.
8. EXPOSURE CONTROLS, PERSONAL PROTECTION
Eyes: Safety glasses or goggles.
Skin: Neoprene, rubber, or butyl rubber gloves.
Ventilation: Does not apply
See Section 2 for Exposure Limits.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Red liquid
Odor: Mild
Boiling Point: More than 300°F
pH: Does not apply
Solubility in Water: Slight
Specific Gravity 1.05 at 80°F
Volatile Organic Compound
(EPA Method 24) 13.5%; 141.75 g/l
Vapor Pressure: Less than 5mm at 80°F
Vapor Density: Not available
Evaporation Rate
(Ether = 1) Not available
10. STABILITY AND REACTIVITY
Stability: Stable
Hazardous Polymerization: Will not occur
Incompatibility: None
Conditions to Avoid: Not available
Hazardous Decomposition
Products (non-thermal): None
11. TOXICOLOGICAL INFORMATION
See Section 3.
LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 04 of 05
Product Name: Permanent Threadlocker 262
Item No.: 26221
12. ECOLOGICAL INFORMATION
No data available
13. DISPOSAL CONSIDERATIONS
Recommended methods of
disposal: Incinerate following EPA and local regulations.
EPA Hazardous Waste
Number NH - Not a RCRA Hazardous Waste Material
14. TRANSPORTATION INFORMATION
DOT (49 CFR 172)
Domestic Ground Transport
Proper Shipping Name: Unrestricted
Hazard Class or
Division: Unrestricted
Identification Number: None
Marine Pollutant: None
IATA
Proper Shipping Name: Unrestricted
Class or Division: Unrestricted
UN or ID Number: None
15. REGULATORY INFORMATION
CA Proposition 65: This product contains Saccharin. No prop65 hazard
warning is necessary if this product is used as
reasonably anticipated.
16. OTHER INFORMATION
Estimated NFPA(R) Code:
Health Hazard: 1
Fire Hazard: 1
Reactivity Hazard: 1
Specific Hazard: Does not apply
Estimated HMIS(R) Code:
Health Hazard: 1
Flammability Hazard: 1
Reactivity Hazards: 1
Personal Protection: See Section 8.
NFPA is a registered trademark of the National Fire Protection Assn.
HMIS is a registered trademark of the National Paint and Coatings Assn.
Prepared By: Stephen Repetto
Title: Research Chemist, Environmental Health & Safety
LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 05 of 05
Product Name: Permanent Threadlocker 262
Item No.: 26221
16. OTHER INFORMATION (continued)
Company: Loctite Corp., 1001 Tr Br Cr, Rocky Hill CT 06067
(24hr.) Phone: (860) 571-5100
Revision Date: January 22, 1996 Revision: 0028
LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 01 of 07
Prism(R) 454 Surf-Insensit Gel Inst Adh
45404
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name: Prism(R) 454 Surf-Insensit Gel Inst Adh
Item No.: 45404 Part of Kit: 00101
Product Type: Cyanoacrylate ester
2. COMPOSITION, INFORMATION ON INGREDIENTS
Ingredients CAS No. %
Ethyl cyanoacrylate 7085-85-0 85-90
Poly (methyl methacrylate) 9011-14-7 5-10
SILICA, AMORPHOUS, FUMED,
CRYSTALLINE-FREE 112945-52-5 5-10
HYDROQUINONE 123-31-9 0.1-0.5
Ingredients which have exposure limits
Exposure Limits (TWA) ACGIH OSHA OTHER
Ingredients (TLV) (PEL)
Ethyl cyanoacrylate None None 2 ppm TWA
9.1 mg/m3
SILICA, AMORPHOUS, FUMED,
CRYSTALLINE-FREE 10 mg/m3 TWA 6 mg/m3 TWA 3 mg/m3 TWA
resp. dust
HYDROQUINONE 2 mg/m3 TWA 2 mg/m3 TWA 2 mg/m3 TWA
4 mg/m3 STEL
Exposure Limits (STEL) ACGIH OSHA
Ingredients (TLV) (PEL)
Ethyl cyanoacrylate (4 ppm) (4 ppm)
(18 mg/m3) (16 mg/m3)
3. HAZARDS IDENTIFICATION
Toxicity: Skin contact may cause burns.
Bonds skin rapidly and strongly.
Skin and eye irritant.
Estimated oral LD50 more than 5000 mg per kg.
Estimated dermal LD50 more than 2000 mg per kg.
Primary Routes of Entry: None known
Signs and symptoms
of Exposure: Vapor is irritating to eyes and mucous membranes
above TLV. Prolonged and repeated overexposure to
vapors may produce symptoms of non-allergic
asthma in sensitive individuals.
LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 02 of 07
Product Name: Prism(R) 454 Surf-Insensit Gel Inst Adh
Item No.: 45404
3. HAZARDS IDENTIFICATION (continued)
Existing Conditions
Aggravated by Exposure: None known
Literature Referenced Carcinogen
Ingredients Target Organ and Other Health Effects NTP IARC OSHA
Ethyl cyanoacrylate ALG IRR RES NO NO NO
Poly (methyl methacrylate) IRR NO N/A NO
SILICA, AMORPHOUS, FUMED,
CRYSTALLINE-FREE NUI NO N/A NO
HYDROQUINONE AC3 BLO BNM CNS EYE IMM IRR MUT NO N/A NO
SKI
-------------------------------------------------------------------------------
Abbreviations
N/A Not Applicable AC3 ACGIH animal carcinogen.
ALG Allergen BLO Blood
BNM Bone Marrow CNS Central nervous system
EYE Eyes IMM Immune system
IRR Irritant MUT Mutagen
NUI Nuisance dust RES Respiratory
SKI Skin
4. FIRST AID MEASURES
Ingestion: Ingestion is not likely. See supplemental page for
emergency procedures.
Inhalation: Remove to fresh air. If symptoms persist,
obtain medical attention.
Skin Contact: Soak in warm water. See supplemental page for
emergency procedures.
Eye Contact: Flush with water. See supplemental page for
emergency procedures.
5. FIRE FIGHTING MEASURES
Flash Point: 150 - 200°F Method: Tag Closed Cup
Recommended
Extinguishing Agents: Carbon dioxide, foam, dry chemical
Hazardous Products formed
by Fire or Thermal Decomp Irritating organic vapors
Unusual Fire or
Explosion Hazards: None
Explosive Limits:
(% by volume in air)Lower Not available
LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 03 of 07
Product Name: Prism(R) 454 Surf-Insensit Gel Inst Adh
Item No.: 45404
5. FIRE FIGHTING MEASURES (continued)
(% by volume in air)Upper Not available
6. ACCIDENTAL RELEASE MEASURES
Steps to be taken in case
of spill or leak: Flood with water to polymerize. Soak up with an
inert absorbent.
7. HANDLING AND STORAGE
Safe Storage: Store at or below 75 deg. F
(Contact Loctite Customer Service 1-800-243-4874 for shelf Life information)
Handling: Avoid contact with skin and eyes. Avoid breathing
vapor.
8. EXPOSURE CONTROLS, PERSONAL PROTECTION
Eyes: Safety glasses or goggles.
Skin: Nitrile or polyethylene gloves and aprons.
Do not use cotton.
See supplemental page for additional information.
Ventilation: Positive down-draft exhaust ventilation should be
provided to maintain vapor concentration below TLV
See Section 2 for Exposure Limits.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Water white gel
Odor: Sharp, irritating
Boiling Point: More than 300°F
pH: Does not apply
Solubility in Water: Polymerized by water
Specific Gravity 1.05
Volatile Organic Compound
(EPA Method 24) 85.4%; 897 grams per liter
Vapor Pressure: Less than 0.2 mm
Vapor Density: Approximately 3
Evaporation Rate
(Ether = 1) Not available
10. STABILITY AND REACTIVITY
Stability: Stable
Hazardous Polymerization: Will not occur
Incompatibility: Polymerized by contact with water, alcohols,
amines, alkalies.
Conditions to Avoid: Not available
LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 04 of 07
Product Name: Prism(R) 454 Surf-Insensit Gel Inst Adh
Item No.: 45404
10. STABILITY AND REACTIVITY (continued)
Hazardous Decomposition
Products (non-thermal): None
11. TOXICOLOGICAL INFORMATION
See Section 3.
12. ECOLOGICAL INFORMATION
No data available
13. DISPOSAL CONSIDERATIONS
Recommended methods of
disposal: Polymerize as above. Incinerate following EPA
and local regulations.
EPA Hazardous Waste
Number NH - Not a RCRA Hazardous Waste Material
14. TRANSPORTATION INFORMATION
DOT (49 CFR 172)
Domestic Ground Transport
Proper Shipping Name: Unrestricted (Not more than 450 liters);
Combustible liquids, n.o.s. (Cyanoacrylate ester)
(More than 450 liters)
Hazard Class or
Division: Unrestricted (Not more than 450 liters)
Combustible liquid (More than 450 liters)
Identification Number: None (Not more than 450 liters);
NA 1993 (More than 450 liters)
Marine Pollutant: None
IATA
Proper Shipping Name: Unrestricted (Not more than one pint);
Other regulated substances (More than one pint)
Class or Division: Unrestricted (Not more than one pint);
Class 9 (More than one pint)
UN or ID Number: None (Not more than one pint)
ID 8027 (More than one pint)
15. REGULATORY INFORMATION
CA Proposition 65: No California Proposition 65 chemicals are known
to be present.
LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 05 of 07
Product Name: Prism(R) 454 Surf-Insensit Gel Inst Adh
Item No.: 45404
16. OTHER INFORMATION
Estimated NFPA(R) Code:
Health Hazard: 2
Fire Hazard: 2
Reactivity Hazard: 1
Specific Hazard: Does not apply
Estimated HMIS(R) Code:
Health Hazard: 2
Flammability Hazard: 2
Reactivity Hazards: 1
Personal Protection: See Section 8.
NFPA is a registered trademark of the National Fire Protection Assn.
HMIS is a registered trademark of the National Paint and Coatings Assn.
Prepared By: Stephen Repetto
Title: Research Chemist, Environmental Health & Safety
Company: Loctite Corp., 1001 Tr Br Cr, Rocky Hill CT 06067
(24hr.) Phone: (860) 571-5100
Revision Date: April 15, 1997 Revision: 0029
LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 06 of 07
Product Name: Prism(R) 454 Surf-Insensit Gel Inst Adh
Item No.: 45404
Supplement
INFORMATION FOR FIRST AID AND CASUALTY ON TREATMENT FOR ADHESION OF
HUMAN SKIN TO ITSELF IF CAUSED BY CYANOACRYLATE ADHESIVES
Cyanoacrylate adhesive is a very fast setting and strong adhesive. It
bonds human tissue including skin in seconds. Experience has shown
that accidents due to cyanoacrylates are handled best by passive,
nonsurgical first aid. Treatment of specific types of accidents are
given below.
SKIN CONTACT
Remove excess adhesive. Soak in warm, soapy water. The adhesive will
come loose from the skin in several hours. Cured adhesive does not
present a health hazard even when bonded to the skin.
Avoid contact with clothes, fabrics, rags, or tissue. Contact with
these materials may cause polymerization. The polymerization of large
amounts of adhesive will generate heat causing smoke, skin burns,
and strong, irritating vapors. Wear nitrile or polyethylene gloves and
apron when handling large amounts of adhesive.
SKIN ADHESION
First immerse the bonded surfaces in warm, soapy water. Peel or roll
the surfaces apart with the aid of a blunt edge, e.g. a spatula or a
teaspoon handle; then remove adhesive from the skin with soap and
water. Do not try to pull surfaces apart with a direct opposing
action.
EYELID TO EYELID OR EYEBALL ADHESION
In the event that eyelids are stuck together or bonded to the eyeball,
wash thoroughly with warm water and apply a gauze patch. The eye will
open without further action, typically in 1-4 days. There will be no
residual damage. Do not try to open the eyes by manipulation.
ADHESIVE ON THE EYEBALL
Cyanoacrylate introduced into the eyes will attach itself to the
eye protein and will disassociate from it over intermittent periods,
generally covering several hours. This will cause periods of weeping
until clearance is achieved. During the period of contamination,
double vision may be experienced together with a lachrymatory effect,
and it is important to understand the cause and realize that
disassociation will normally occur within a matter of hours, even with
gross contamination.
MOUTH
If lips are accidentally stuck together, apply lots of warm water to
the lips and encourage maximum wetting and pressure from saliva inside
the mouth. Peel or roll lips apart. Do not try to pull the lips
LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 07 of 07
Product Name: Prism(R) 454 Surf-Insensit Gel Inst Adh
Item No.: 45404
Supplement
with direct opposing action.
It is almost impossible to swallow cyanoacrylate. The adhesive
solidifies and adheres in the mouth. Saliva will lift the adhesive in
one half to two days. In case a lump forms in the mouth, position the
patient to prevent ingestion of the lump when it detaches.
BURNS
Cyanoacrylates give off heat on solidification. In rare cases a large
drop will increase in temperature enough to cause a burn.
Burns should be treated normally after the lump of cyanoacrylate is
released from the tissue as described above.
SURGERY
It should never be necessary to use such a drastic method to separate
accidentally bonded skin.
LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 01 of 05
Gasket Eliminator(R) 518 Inst Seal/Flange Sealant
51831
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name: Gasket Eliminator(R) 518 Inst Seal/Flange Sealant
Item No.: 51831 Part of Kit: 00101
Product Type: Anaerobic
2. COMPOSITION, INFORMATION ON INGREDIENTS
Ingredients CAS No. %
Polyurethane methacrylate Proprietary 70-75
Polyglycol dimethacrylate 25852-47-5 5-10
SILICA, AMORPHOUS, FUMED,
CRYSTALLINE-FREE 112945-52-5 5-10
ACRYLIC ACID* 79-10-7 5-7
CUMENE HYDROPEROXIDE* 80-15-9 1-3
ETHYLENE GLYCOL* 107-21-1 1-3
1-Acetyl-2-phenylhydrazine 114-83-0 0.1-1
SACCHARIN 81-07-2 0.1-1
* This component is listed as a SARA Section 313 Toxic Chemical.
Ingredients which have exposure limits
Exposure Limits (TWA) ACGIH OSHA OTHER
Ingredients (TLV) (PEL)
SILICA, AMORPHOUS, FUMED,
CRYSTALLINE-FREE 10 mg/m3 TWA 6 mg/m3 TWA 3 mg/m3 TWA
resp. dust
ACRYLIC ACID 2 ppm TWA skin 10 ppm TWA skin 1 ppm TWA skin
5.9 mg/m3 skin 30 mg/m3 skin 3 ppm STEL skin
ETHYLENE GLYCOL None 50 ppm ceiling None
125mg/m3ceiling
Exposure Limits (STEL) ACGIH OSHA
Ingredients (TLV) (PEL)
ETHYLENE GLYCOL 39.4ppm ceil ar None
100mg/m3 ceil a
3. HAZARDS IDENTIFICATION
Toxicity: Liquid is an eye and skin irritant.
Vapors may irritate eye, nose and throat.
Estimated oral LD50 more than 5000 mg/kg.
Estimated dermal LD50 more than 2000 mg/kg.
Primary Routes of Entry: None known
LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 02 of 05
Product Name: Gasket Eliminator(R) 518 Inst Seal/Flange Sealant
Item No.: 51831
3. HAZARDS IDENTIFICATION (continued)
Signs and symptoms
of Exposure: Irritation of eyes, skin , nose or throat. May
cause dermatitis on,prolonged contact in sensitive
individuals.
Existing Conditions
Aggravated by Exposure: Acrylic acid: Upper respiratory and lung diseases.
Literature Referenced Carcinogen
Ingredients Target Organ and Other Health Effects NTP IARC OSHA
Polyurethane methacrylate No Data NO NO NO
Polyglycol dimethacrylate ALG IRR NO NO NO
SILICA, AMORPHOUS, FUMED,
CRYSTALLINE-FREE NUI NO N/A NO
ACRYLIC ACID AC4 ALG COR IRR NO N/A NO
CUMENE HYDROPEROXIDE ALG CNS COR IRR MUT NO NO NO
ETHYLENE GLYCOL AC4 CNS DEV IRR KID MET NO NO NO
1-Acetyl-2-phenylhydrazine ALG NO NO NO
SACCHARIN No Data YES 2B NO
-------------------------------------------------------------------------------
Abbreviations
N/A Not Applicable 2B Possibly carcinogenic to humans
AC4 ACGIH-Unclassifiable as human carc. ALG Allergen
CNS Central nervous system COR Corrosive
DEV Developmental IRR Irritant
KID Kidney MET Metabolic
MUT Mutagen NUI Nuisance dust
4. FIRST AID MEASURES
Ingestion: Do not induce vomiting. Keep individual calm.
Obtain medical attention.
Inhalation: Remove to fresh air. If symptoms persist, obtain
medical attention.
Skin Contact: Wash thoroughly with soap and water
Eye Contact: Flush at least 15 minutes with water. Obtain
medical attention.
5. FIRE FIGHTING MEASURES
Flash Point: More than 200°F Method: Tag Closed Cup
Recommended
Extinguishing Agents: Carbon dioxide, foam, dry chemical
LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 03 of 05
Product Name: Gasket Eliminator(R) 518 Inst Seal/Flange Sealant
Item No.: 51831
5. FIRE FIGHTING MEASURES (continued)
Hazardous Products formed
by Fire or Thermal Decomp Irritating organic vapors.
Unusual Fire or
Explosion Hazards: None
Explosive Limits:
(% by volume in air)Lower 2.0% Acrylic acid
(% by volume in air)Upper 8.0% Acrylic acid
6. ACCIDENTAL RELEASE MEASURES
Steps to be taken in case
of spill or leak: Scrape up as much as possible and store in a
partly filled, closed container until disposal.
Residues may be cleaned up with solvent.
7. HANDLING AND STORAGE
Safe Storage: Store below 100 deg. F
(Contact Loctite Customer Service 1-800-243-4874 for shelf Life information)
Handling: Avoid skin and eye contact. Avoid breathing vapor
8. EXPOSURE CONTROLS, PERSONAL PROTECTION
Eyes: Safety glasses or goggles.
Skin: Rubber or plastic gloves.
Ventilation: Sufficient to maintain vapor concentration below
TLV
See Section 2 for Exposure Limits.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Red gel
Odor: Mild
Boiling Point: More than 300°F
pH: Does not apply
Solubility in Water: Low
Specific Gravity 1.1 at 80°F
Volatile Organic Compound
(EPA Method 24) 13.0%; 143 grams per liter
Vapor Pressure: Less than 5mm at 80°F
Vapor Density: Not available
Evaporation Rate
(Ether = 1) Not available
LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 04 of 05
Product Name: Gasket Eliminator(R) 518 Inst Seal/Flange Sealant
Item No.: 51831
10. STABILITY AND REACTIVITY
Stability: Stable
Hazardous Polymerization: Will not occur
Incompatibility: None
Conditions to Avoid: Not available
Hazardous Decomposition
Products (non-thermal): None
11. TOXICOLOGICAL INFORMATION
See Section 3.
12. ECOLOGICAL INFORMATION
No data available
13. DISPOSAL CONSIDERATIONS
Recommended methods of
disposal: Incinerate following EPA and local regulations.
EPA Hazardous Waste
Number NH - Not a RCRA Hazardous Waste Material
14. TRANSPORTATION INFORMATION
DOT (49 CFR 172)
Domestic Ground Transport
Proper Shipping Name: Unrestricted
Hazard Class or
Division: Unrestricted
Identification Number: None
Marine Pollutant: None
IATA
Proper Shipping Name: Unrestricted
Class or Division: Unrestricted
UN or ID Number: None
15. REGULATORY INFORMATION
CA Proposition 65: WARNING: This product contains chemicals known to
the State of California to cause cancer
and birth defects or other reproductive
harm.
Ethylene Oxide
This product contains Saccharin. No Prop65 hazard
warning is necessary if this product is used as
reasonably anticipated.
LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 05 of 05
Product Name: Gasket Eliminator(R) 518 Inst Seal/Flange Sealant
Item No.: 51831
16. OTHER INFORMATION
Estimated NFPA(R) Code:
Health Hazard: 2
Fire Hazard: 1
Reactivity Hazard: 1
Specific Hazard: Does not apply
Estimated HMIS(R) Code:
Health Hazard: 2
Flammability Hazard: 1
Reactivity Hazards: 1
Personal Protection: See Section 8.
NFPA is a registered trademark of the National Fire Protection Assn.
HMIS is a registered trademark of the National Paint and Coatings Assn.
Prepared By: Stephen Repetto
Title: Research Chemist, Environmental Health & Safety
Company: Loctite Corp., 1001 Tr Br Cr, Rocky Hill CT 06067
(24hr.) Phone: (860) 571-5100
Revision Date: April 15, 1997 Revision: 0031
LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 01 of 05
PST(R) Pipe Sealant 565 Thread Sealant
56531
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name: PST(R) Pipe Sealant 565 Thread Sealant
Item No.: 56531 Part of Kit: 00101
Product Type: Anaerobic
2. COMPOSITION, INFORMATION ON INGREDIENTS
Ingredients CAS No. %
Polyglycol dimethacrylate 25852-47-5 35-40
Polymeric plasticizer 68332-62-7 25-30
Cellulose ester 9004-36-8 15-20
Poly(tetrafluoroethylene) 9002-84-0 5-10
SILICA, AMORPHOUS, FUMED,
CRYSTALLINE-FREE 112945-52-5 3-5
TITANIUM DIOXIDE 13463-67-7 3-5
CUMENE HYDROPEROXIDE* 80-15-9 1-3
SACCHARIN 81-07-2 1-3
N,N-Dialkyltoluidines 613-48-9 0.1-1
Poly(ethylene) 9002-88-4 0.1-0.5
* This component is listed as a SARA Section 313 Toxic Chemical.
Ingredients which have exposure limits
Exposure Limits (TWA) ACGIH OSHA OTHER
Ingredients (TLV) (PEL)
SILICA, AMORPHOUS, FUMED,
CRYSTALLINE-FREE 10 mg/m3 TWA 6 mg/m3 TWA 3 mg/m3 TWA
resp. dust
TITANIUM DIOXIDE 10 mg/m3 dust 15 mg/m3 dust None
5 mg/m3 resp
Exposure Limits (STEL) ACGIH OSHA
Ingredients (TLV) (PEL)
3. HAZARDS IDENTIFICATION
Toxicity: Moderate eye irritant.
Estimated Oral LD50 greater than 5,000 mg/kg.
Estimated Dermal LD50 greater than 2,000 mg/kg.
Primary Routes of Entry: None known
Signs and symptoms
of Exposure: May cause dermatitis on prolonged contact in
sensitive individuals
LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 02 of 05
Product Name: PST(R) Pipe Sealant 565 Thread Sealant
Item No.: 56531
3. HAZARDS IDENTIFICATION (continued)
Existing Conditions
Aggravated by Exposure: None known
Literature Referenced Carcinogen
Ingredients Target Organ and Other Health Effects NTP IARC OSHA
Polyglycol dimethacrylate ALG IRR NO NO NO
Polymeric plasticizer No Data NO NO NO
Cellulose ester No Data NO NO NO
Poly(tetrafluoroethylene) No Data NO N/A NO
SILICA, AMORPHOUS, FUMED,
CRYSTALLINE-FREE NUI NO N/A NO
TITANIUM DIOXIDE AC4 IRR NUI NO NO NO
CUMENE HYDROPEROXIDE ALG CNS COR IRR MUT NO NO NO
SACCHARIN No Data YES 2B NO
N,N-Dialkyltoluidines No Data NO NO NO
Poly(ethylene) No Data NO N/A NO
-------------------------------------------------------------------------------
Abbreviations
N/A Not Applicable 2B Possibly carcinogenic to humans
AC4 ACGIH-Unclassifiable as human carc. ALG Allergen
CNS Central nervous system COR Corrosive
IRR Irritant MUT Mutagen
NUI Nuisance dust
4. FIRST AID MEASURES
Ingestion: Do not induce vomiting. Keep individual calm.
Obtain medical attention.
Inhalation: Does not apply
Skin Contact: Wash with soap and water.
Eye Contact: Flush at least 15 minutes with water. Obtain
medical attention.
5. FIRE FIGHTING MEASURES
Flash Point: More than 200°F Method: Tag Closed Cup
Recommended
Extinguishing Agents: Carbon dioxide, foam, dry chemical
Hazardous Products formed
by Fire or Thermal Decomp Irritating organic vapors. Toxic fluorides.
Unusual Fire or
Explosion Hazards: None
Explosive Limits:
LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 03 of 05
Product Name: PST(R) Pipe Sealant 565 Thread Sealant
Item No.: 56531
5. FIRE FIGHTING MEASURES (continued)
(% by volume in air)Lower Not available
(% by volume in air)Upper Not available
6. ACCIDENTAL RELEASE MEASURES
Steps to be taken in case
of spill or leak: Soak up in an inert absorbent. Store in a partly
filled, closed container until disposal.
7. HANDLING AND STORAGE
Safe Storage: Store below 100°F
(Contact Loctite Customer Service 1-800-243-4874 for shelf Life information)
Handling: Avoid prolonged skin contact. Keep away from eyes.
8. EXPOSURE CONTROLS, PERSONAL PROTECTION
Eyes: Safety glasses or goggles.
Skin: Rubber or plastic gloves.
Ventilation: Does not apply
See Section 2 for Exposure Limits.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: White paste
Odor: Mild
Boiling Point: More than 300°F
pH: Does not apply
Solubility in Water: Slight
Specific Gravity 1.1 at 80°F
Volatile Organic Compound
(EPA Method 24) 7.9%; 87 grams per liter
Vapor Pressure: Less than 5mm at 80°F
Vapor Density: Not available
Evaporation Rate
(Ether = 1) Not available
10. STABILITY AND REACTIVITY
Stability: Stable
Hazardous Polymerization: Will not occur
Incompatibility: None
Conditions to Avoid: Not available
Hazardous Decomposition
Products (non-thermal): Irritating organic and inorganic vapors. Toxic
fluorides.
LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 04 of 05
Product Name: PST(R) Pipe Sealant 565 Thread Sealant
Item No.: 56531
11. TOXICOLOGICAL INFORMATION
See Section 3.
12. ECOLOGICAL INFORMATION
No data available
13. DISPOSAL CONSIDERATIONS
Recommended methods of
disposal: Incinerate or dispose of in approved landfill
for non-RCRA materials following local, state and
federal regulations.
EPA Hazardous Waste
Number NH - Not a RCRA Hazardous Waste Material
14. TRANSPORTATION INFORMATION
DOT (49 CFR 172)
Domestic Ground Transport
Proper Shipping Name: Unrestricted
Hazard Class or
Division: Unrestricted
Identification Number: None
Marine Pollutant: None
IATA
Proper Shipping Name: Unrestricted
Class or Division: Unrestricted
UN or ID Number: None
15. REGULATORY INFORMATION
CA Proposition 65: This product contains Saccharin. No prop65 hazard
warning is necessary if this product is used as
reasonably anticipated.
16. OTHER INFORMATION
Estimated NFPA(R) Code:
Health Hazard: 1
Fire Hazard: 1
Reactivity Hazard: 1
Specific Hazard: Does not apply
Estimated HMIS(R) Code:
Health Hazard: 1
Flammability Hazard: 1
Reactivity Hazards: 1
Personal Protection: See Section 8.
LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 05 of 05
Product Name: PST(R) Pipe Sealant 565 Thread Sealant
Item No.: 56531
16. OTHER INFORMATION (continued)
NFPA is a registered trademark of the National Fire Protection Assn.
HMIS is a registered trademark of the National Paint and Coatings Assn.
Prepared By: Stephen Repetto
Title: Research Chemist, Health and Safety
Company: Loctite Corp., 1001 Tr Br Cr, Rocky Hill CT 06067
(24hr.) Phone: (860) 571-5100
Revision Date: April 15, 1997 Revision: 0029
LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 01 of 05
Superflex(R) Ultra-Blue(TM) Silicone
58730
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name: Superflex(R) Ultra-Blue(TM) Silicone
Item No.: 58730 Part of Kit: 00101
Product Type: RTV Silicone
2. COMPOSITION, INFORMATION ON INGREDIENTS
Ingredients CAS No. %
Poly(dimethylsiloxane),
hydroxy terminated 70131-67-8 35-40
Calcium carbonate 471-34-1 30-35
Poly(dimethylsiloxane),
dimethyl 63148-62-9 15-20
Modified silicon dioxide 68611-44-9 5-10
Vinyl oximinosilane 2224-33-1 3-5
Substituted silane Proprietary 0.1-1
Methyl ethyl ketoxime Proprietary ***
***When this product is exposed to moisture, 5-10% methyl ethyl
ketoxime may be formed.
Ingredients which have exposure limits
Exposure Limits (TWA) ACGIH OSHA OTHER
Ingredients (TLV) (PEL)
Calcium carbonate 10 mg/m3 dust 15 mg/m3 dust None
5 mg/m3 respir.
Modified silicon dioxide 10 mg/m3 6 mg/m3 6 mg/m3
Methyl ethyl ketoxime None None 3 ppm TWA
10 ppm STEL
Exposure Limits (STEL) ACGIH OSHA
Ingredients (TLV) (PEL)
3. HAZARDS IDENTIFICATION
Toxicity: Eye and skin irritant. Moderately toxic by
ingestion. When heated to temperatures above
300°F (150°F) in the presence of air, this
product can form formaldehyde vapors. Formaldehyde
is a potential cancer hazard and a known skin
and respiratory sensitizer.
Vapors irritate eyes, nose and throat.
LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 02 of 05
Product Name: Superflex(R) Ultra-Blue(TM) Silicone
Item No.: 58730
3. HAZARDS IDENTIFICATION (continued)
Safe handling conditions may be maintained by
keeping vapor concentrations below the OSHA
permissible limit for formaldehyde.
Primary Routes of Entry: Skin absorbtion, ingestion, inhalation.
Signs and symptoms
of Exposure: Methyl ethyl ketoxime produced during cure
is toxic and irritates eyes, nose and throat.
Existing Conditions
Aggravated by Exposure: Dermatitis
Literature Referenced Carcinogen
Ingredients Target Organ and Other Health Effects NTP IARC OSHA
Poly(dimethylsiloxane),
hydroxy terminated No Data NO NO NO
Calcium carbonate NUI NO NO NO
Poly(dimethylsiloxane),
dimethyl IRR NO NO NO
Modified silicon dioxide No Data NO NO NO
Vinyl oximinosilane No Data NO NO NO
Substituted silane No Data NO NO NO
Methyl ethyl ketoxime ALG BLO CNS IRR NO NO NO
-------------------------------------------------------------------------------
Abbreviations
ALG Allergen BLO Blood
CNS Central nervous system IRR Irritant
NUI Nuisance dust
4. FIRST AID MEASURES
Ingestion: Do not induce vomiting. Keep individual calm.
Obtain medical attention
Inhalation: Remove to fresh air. If symptoms persist, obtain
medical attention.
Skin Contact: Wipe off paste with paper towel or cloth.
Wash thoroughly with soap and water
Eye Contact: Flush at least 15 minutes with water. Obtain
medical attention.
5. FIRE FIGHTING MEASURES
Flash Point: More than 200°F Method: Tag Closed Cup
Recommended
Extinguishing Agents: Carbon dioxide, foam, dry chemical
LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 03 of 05
Product Name: Superflex(R) Ultra-Blue(TM) Silicone
Item No.: 58730
5. FIRE FIGHTING MEASURES (continued)
Hazardous Products formed
by Fire or Thermal Decomp Formaldehyde, silica fume
Unusual Fire or
Explosion Hazards: None
Explosive Limits:
(% by volume in air)Lower Not available
(% by volume in air)Upper Not available
6. ACCIDENTAL RELEASE MEASURES
Steps to be taken in case
of spill or leak: Wipe or scrape up spilled material. Maintain good
ventilation for large spills. Place scrap
material in a well ventilated area and allow to
cure to rubber.
7. HANDLING AND STORAGE
Safe Storage: Store in a dry area below 90°F. Keep
containers closed when not in use.
(Contact Loctite Customer Service 1-800-243-4874 for shelf Life information)
Handling: Avoid skin and eye contact. Avoid breathing vapor
Do not wear contact lenses while applying material
Vapor may be trapped under lens.
8. EXPOSURE CONTROLS, PERSONAL PROTECTION
Eyes: Safety glasses or goggles.
Skin: Rubber or plastic gloves.
Ventilation: Provide local ventilation for prolonged use in a
confined area.
See Section 2 for Exposure Limits.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Blue paste
Odor: Mild
Boiling Point: Not Applicable, Polymeric
pH: 7-8
Solubility in Water: Polymerized
Specific Gravity 1.3
Volatile Organic Compound
(EPA Method 24) 3.9%; 50.7 grams per liter
Vapor Pressure: Less than 5mm at 70°F
Vapor Density: 3.0
LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 04 of 05
Product Name: Superflex(R) Ultra-Blue(TM) Silicone
Item No.: 58730
9. PHYSICAL AND CHEMICAL PROPERTIES (continued)
Evaporation Rate
(Ether = 1) Not available
10. STABILITY AND REACTIVITY
Stability: Stable
Hazardous Polymerization: Will not occur
Incompatibility: Strong oxidizers. Polymerized by contact with
moisture.
Conditions to Avoid: Not available
Hazardous Decomposition
Products (non-thermal): Methyl ethyl ketoxime
11. TOXICOLOGICAL INFORMATION
See Section 3.
12. ECOLOGICAL INFORMATION
No data available
13. DISPOSAL CONSIDERATIONS
Recommended methods of
disposal: Cured rubber can be incinerated following EPA
and local regulations
EPA Hazardous Waste
Number NH - Not a RCRA Hazardous Waste Material
14. TRANSPORTATION INFORMATION
DOT (49 CFR 172)
Domestic Ground Transport
Proper Shipping Name: Unrestricted
Hazard Class or
Division: Unrestricted
Identification Number: None
Marine Pollutant: None
IATA
Proper Shipping Name: Unrestricted
Class or Division: Unrestricted
UN or ID Number: None
15. REGULATORY INFORMATION
CA Proposition 65: WARNING: This product contains chemicals known to
the State of California to cause birth
defects or other reproductive harm.
LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 05 of 05
Product Name: Superflex(R) Ultra-Blue(TM) Silicone
Item No.: 58730
15. REGULATORY INFORMATION (continued)
traces of toluene
16. OTHER INFORMATION
Estimated NFPA(R) Code:
Health Hazard: 1
Fire Hazard: 1
Reactivity Hazard: 0
Specific Hazard: No water.
Estimated HMIS(R) Code:
Health Hazard: 1
Flammability Hazard: 1
Reactivity Hazards: 0
Personal Protection: See Section 8.
NFPA is a registered trademark of the National Fire Protection Assn.
HMIS is a registered trademark of the National Paint and Coatings Assn.
Prepared By: Stephen Repetto
Title: Research Chemist, Environmental Health & Safety
Company: Loctite Corp., 1001 Tr Br Cr, Rocky Hill CT 06067
(24hr.) Phone: (860) 571-5100
Revision Date: January 22, 1996 Revision: 0031
LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 01 of 05
660 Quick Metal(R) Press Fit Repair Retaining Cmpd
66010
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name: 660 Quick Metal(R) Press Fit Repair Retaining Cmpd
Item No.: 66010 Part of Kit: 00101
Product Type: Anaerobic
2. COMPOSITION, INFORMATION ON INGREDIENTS
Ingredients CAS No. %
Aromatic dimethacrylate ester 24448-20-2 40-45
Hydroxyalkyl methacrylate 27813-02-1 30-35
Bisphenol A fumarate resin 39382-25-7 5-10
SILICA, AMORPHOUS, FUMED,
CRYSTALLINE-FREE 112945-52-5 5-10
Poly(vinyl acetate) 9003-20-7 3-5
CUMENE HYDROPEROXIDE* 80-15-9 1-3
METHYL ALCOHOL* 67-56-1 1-3
TITANIUM DIOXIDE 13463-67-7 1-3
1-Acetyl-2-phenylhydrazine 114-83-0 0.1-1
N,N-Dialkyltoluidines 613-48-9 0.1-1
MALEIC ACID 110-16-7 0.1-1
SACCHARIN 81-07-2 0.1-1
* This component is listed as a SARA Section 313 Toxic Chemical.
Ingredients which have exposure limits
Exposure Limits (TWA) ACGIH OSHA OTHER
Ingredients (TLV) (PEL)
Hydroxyalkyl methacrylate None None 3 ppm ceiling
SILICA, AMORPHOUS, FUMED,
CRYSTALLINE-FREE 10 mg/m3 TWA 6 mg/m3 TWA 3 mg/m3 TWA
resp. dust
METHYL ALCOHOL 200ppm TWA skin 200ppm TWA skin None
262 mg/m3 skin 262 mg/m3 skin
TITANIUM DIOXIDE 10 mg/m3 dust 15 mg/m3 dust None
5 mg/m3 resp
Exposure Limits (STEL) ACGIH OSHA
Ingredients (TLV) (PEL)
METHYL ALCOHOL 250 ppm skin 250 ppm skin
328 mg/m3 skin 325 mg/m3 skin
LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 02 of 05
Product Name: 660 Quick Metal(R) Press Fit Repair Retaining Cmpd
Item No.: 66010
3. HAZARDS IDENTIFICATION
Toxicity: Severe eye irritant. Moderate skin irritant.
Possible inhalation irritant. May be harmful if
swallowed. May cause kidney or liver damage.
Estimated oral LD50 more than 5000 mg/kg.
Estimated dermal LD50 more than 2000 mg/kg.
Primary Routes of Entry: Eye, skin, inhalation, ingestion.
Signs and symptoms
of Exposure: May cause severe dermatitis on prolonged contact
in sensitive individuals.
Existing Conditions
Aggravated by Exposure: None known
Literature Referenced Carcinogen
Ingredients Target Organ and Other Health Effects NTP IARC OSHA
Aromatic dimethacrylate ester ALG IRR NO NO NO
Hydroxyalkyl methacrylate ALG IRR NO NO NO
Bisphenol A fumarate resin ALG IRR NO NO NO
SILICA, AMORPHOUS, FUMED,
CRYSTALLINE-FREE NUI NO N/A NO
Poly(vinyl acetate) No Data NO N/A NO
CUMENE HYDROPEROXIDE ALG CNS COR IRR MUT NO NO NO
METHYL ALCOHOL EYE IRR MET NER NO NO NO
TITANIUM DIOXIDE AC4 IRR NUI NO NO NO
1-Acetyl-2-phenylhydrazine ALG NO NO NO
N,N-Dialkyltoluidines No Data NO NO NO
MALEIC ACID IRR NO NO NO
SACCHARIN No Data YES 2B NO
-------------------------------------------------------------------------------
Abbreviations
N/A Not Applicable 2B Possibly carcinogenic to humans
AC4 ACGIH-Unclassifiable as human carc. ALG Allergen
CNS Central nervous system COR Corrosive
EYE Eyes IRR Irritant
MET Metabolic MUT Mutagen
NER Nervous System NUI Nuisance dust
4. FIRST AID MEASURES
Ingestion: Do not induce vomiting. Keep individual calm.
Obtain medical attention
Inhalation: Remove to fresh air. If symptoms persist,
obtain medical attention.
Skin Contact: Wash thoroughly with soap and water
LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 03 of 05
Product Name: 660 Quick Metal(R) Press Fit Repair Retaining Cmpd
Item No.: 66010
4. FIRST AID MEASURES (continued)
Eye Contact: Flush at least 15 minutes with water. Obtain
medical attention.
5. FIRE FIGHTING MEASURES
Flash Point: More than 200°F Method: Tag Closed Cup
Recommended
Extinguishing Agents: Carbon dioxide, foam, dry chemical
Hazardous Products formed
by Fire or Thermal Decomp Oxides of carbon
Unusual Fire or
Explosion Hazards: None
Explosive Limits:
(% by volume in air)Lower Methanol: 6%
(% by volume in air)Upper Methanol: 36%
6. ACCIDENTAL RELEASE MEASURES
Steps to be taken in case
of spill or leak: Soak up in an inert absorbent. Store in a partly
filled, closed container until disposal.
7. HANDLING AND STORAGE
Safe Storage: Store below 100°F
(Contact Loctite Customer Service 1-800-243-4874 for shelf Life information)
Handling: Avoid prolonged skin contact. Keep away from eyes.
8. EXPOSURE CONTROLS, PERSONAL PROTECTION
Eyes: Safety glasses or goggles.
Skin: Rubber or plastic gloves.
Ventilation: Sufficient to maintain vapor concentration
below TLV.
See Section 2 for Exposure Limits.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Silver paste
Odor: Mild
Boiling Point: Greater than 300°F
pH: Does not apply
Solubility in Water: Slight
Specific Gravity 1.10 at 75°F
Volatile Organic Compound
(EPA Method 24) 38.1%; 419 grams per liter
LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 04 of 05
Product Name: 660 Quick Metal(R) Press Fit Repair Retaining Cmpd
Item No.: 66010
9. PHYSICAL AND CHEMICAL PROPERTIES (continued)
Vapor Pressure: Less than 5mm at 80°F
Vapor Density: Not available
Evaporation Rate
(Ether = 1) Not available
10. STABILITY AND REACTIVITY
Stability: Stable
Hazardous Polymerization: Hazardous polymerization may occur if over-
catalyzed or insufficiently aerated after
catalyzation. This polymerization is exothermic.
Incompatibility: Reducing agents
Conditions to Avoid: Not available
Hazardous Decomposition
Products (non-thermal): None
11. TOXICOLOGICAL INFORMATION
See Section 3.
12. ECOLOGICAL INFORMATION
No data available
13. DISPOSAL CONSIDERATIONS
Recommended methods of
disposal: Incinerate following EPA and local regulations.
EPA Hazardous Waste
Number NH - Not a RCRA Hazardous Waste Material
14. TRANSPORTATION INFORMATION
DOT (49 CFR 172)
Domestic Ground Transport
Proper Shipping Name: Unrestricted
Hazard Class or
Division: Unrestricted
Identification Number: None
Marine Pollutant: None
IATA
Proper Shipping Name: Unrestricted
Class or Division: Unrestricted
UN or ID Number: None
LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 05 of 05
Product Name: 660 Quick Metal(R) Press Fit Repair Retaining Cmpd
Item No.: 66010
15. REGULATORY INFORMATION
CA Proposition 65: This product contains Saccharin. No prop65 hazard
warning is necessary if this product is used as
reasonably anticipated.
16. OTHER INFORMATION
Estimated NFPA(R) Code:
Health Hazard: 1
Fire Hazard: 1
Reactivity Hazard: 1
Specific Hazard: Does not apply
Estimated HMIS(R) Code:
Health Hazard: 1
Flammability Hazard: 1
Reactivity Hazards: 1
Personal Protection: See Section 8.
NFPA is a registered trademark of the National Fire Protection Assn.
HMIS is a registered trademark of the National Paint and Coatings Assn.
Prepared By: Stephen Repetto
Title: Research Chemist, Environmental Health & Safety
Company: Loctite Corp., 1001 Tr Br Cr, Rocky Hill CT 06067
(24hr.) Phone: (860) 571-5100
Revision Date: April 15, 1997 Revision: 0034
LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 01 of 05
LOCQUIC(R) PRIMER N 7649
21348
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name: LOCQUIC(R) PRIMER N 7649
Item No.: 21348 Part of Kit: 00101
Product Type: Aerosol accelerator
2. COMPOSITION, INFORMATION ON INGREDIENTS
Ingredients CAS No. %
ACETONE 67-64-1 75-80
ISOBUTANE 75-28-5 20-25
2-Ethylhexanoic acid 149-57-5 0.1-1
Organo-copper compound 22221-10-9 0.1-1
Trialkylammonium Carboxylate 58823-74-8 0.1-1
Ingredients which have exposure limits
Exposure Limits (TWA) ACGIH OSHA OTHER
Ingredients (TLV) (PEL)
ACETONE 750 ppm TWA 750 ppm TWA None
1780 mg/m3 1800 mg/m3
Organo-copper compound Cu 0.2mg/m3fume Cu 0.1mg/m3 None
Cu 1 mg/m3 dust Cu 1 mg/m3 dust
Exposure Limits (STEL) ACGIH OSHA
Ingredients (TLV) (PEL)
ACETONE 1000 ppm 1000 ppm
2380 mg/m3 2400 mg/m3
3. HAZARDS IDENTIFICATION
Toxicity: Harmful if inhaled or swallowed.
Possible eye and respiratory irritant.
Narcotic at high concentrations.
Prolonged inhalation may cause headaches.
Moderately toxic by ingestion
Liquid may defat skin.
Primary Routes of Entry: Inhalation, ingestion, contact.
Signs and symptoms
of Exposure: Vapors irritate eyes, nose and throat.
Liquid is an eye irritant and may irritate skin.
Existing Conditions
Aggravated by Exposure: None known
LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 02 of 05
Product Name: LOCQUIC(R) PRIMER N 7649
Item No.: 21348
3. HAZARDS IDENTIFICATION (continued)
Literature Referenced Carcinogen
Ingredients Target Organ and Other Health Effects NTP IARC OSHA
ACETONE BLO CNS IRR NO NO NO
ISOBUTANE CAR CNS LUN NO NO NO
2-Ethylhexanoic acid IRR NO NO NO
Organo-copper compound No Data NO NO NO
Trialkylammonium Carboxylate No Data NO NO NO
-------------------------------------------------------------------------------
Abbreviations
BLO Blood CAR Cardiac
CNS Central nervous system IRR Irritant
LUN Lung
4. FIRST AID MEASURES
Ingestion: Give water to dilute. Do not induce vomiting.
Keep individual calm. Obtain medical attention.
Inhalation: Remove to fresh air. If symptoms persist, obtain
medical attention.
Skin Contact: Wash with soap and water.
Eye Contact: Flush with water for at least 15 minutes. Obtain
medical attention.
5. FIRE FIGHTING MEASURES
Flash Point: Approximately -4°F(Base) Method: Tag Closed Cup
Recommended
Extinguishing Agents: Carbon dioxide, foam, dry chemical
Hazardous Products formed
by Fire or Thermal Decomp Irritating organic vapors
Unusual Fire or
Explosion Hazards: Cans may burst in fires.
Explosive Limits:
(% by volume in air)Lower Acetone: 2.6%
Isobutane: 1.8%
(% by volume in air)Upper Acetone: 13%
Isobutane: 8.4%
6. ACCIDENTAL RELEASE MEASURES
Steps to be taken in case
of spill or leak: Avoid flame and sparks. Maintain adequate
ventilation. Soak up in an inert absorbent and
LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 03 of 05
Product Name: LOCQUIC(R) PRIMER N 7649
Item No.: 21348
6. ACCIDENTAL RELEASE MEASURES (continued)
store in a closed container until disposal.
7. HANDLING AND STORAGE
Safe Storage: Store away from flame and sparks and below 120F
(Contact Loctite Customer Service 1-800-243-4874 for shelf Life information)
Handling: Avoid prolonged breathing of fumes. Avoid skin
or eye contact. Do not use near heat, sparks, or
open flame.
8. EXPOSURE CONTROLS, PERSONAL PROTECTION
Eyes: Safety glasses or goggles.
Skin: Rubber or plastic gloves.
Ventilation: Sufficient to maintain vapor concentration
below TLV.
See Section 2 for Exposure Limits.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Green liquid (Base only)
Odor: Acetone
Boiling Point: 133°F (Base only)
pH: Does not apply
Solubility in Water: Miscible
Specific Gravity 0.7936 (Base only)
Volatile Organic Compound
(EPA Method 24) 1.48%;11.7 grams per liter of material (Base only)
Vapor Pressure: Approximately 172 mm Hg at 68°F (Base only)
Vapor Density: Not available
Evaporation Rate
(Ether = 1) 1.9 (Base only)
10. STABILITY AND REACTIVITY
Stability: Stable
Hazardous Polymerization: Will not occur
Incompatibility: Strong oxidizers, peroxides
Conditions to Avoid: Not available
Hazardous Decomposition
Products (non-thermal): None
11. TOXICOLOGICAL INFORMATION
See Section 3.
LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 04 of 05
Product Name: LOCQUIC(R) PRIMER N 7649
Item No.: 21348
12. ECOLOGICAL INFORMATION
No data available
13. DISPOSAL CONSIDERATIONS
Recommended methods of
disposal: Use disposal service licensed to handle flammable
aerosols.
EPA Hazardous Waste
Number D001 - Hazardous waste per 40CFR 261.21
14. TRANSPORTATION INFORMATION
DOT (49 CFR 172)
Domestic Ground Transport
Proper Shipping Name: Consumer Commodity
Hazard Class or
Division: ORM-D
Identification Number: None
Marine Pollutant: None
IATA
Proper Shipping Name: Aerosols, flammable, n.o.s.
Class or Division: Division 2.1
UN or ID Number: UN 1950
15. REGULATORY INFORMATION
CA Proposition 65: WARNING: This product contains a chemical known to
the State of California to cause cancer
and birth defects or other reproductive
harm.
Traces of lead and nickel
16. OTHER INFORMATION
Estimated NFPA(R) Code:
Health Hazard: 2
Fire Hazard: 4
Reactivity Hazard: 0
Specific Hazard: Does not apply
Estimated HMIS(R) Code:
Health Hazard: 2
Flammability Hazard: 4
Reactivity Hazards: 0
Personal Protection: See Section 8.
NFPA is a registered trademark of the National Fire Protection Assn.
HMIS is a registered trademark of the National Paint and Coatings Assn.
LOCTITE CORPORATION 07/02/97
ROCKY HILL, CONNECTICUT 06067
EMERGENCY PHONE: (860) 571-5100
MATERIAL SAFETY DATA SHEET Page 05 of 05
Product Name: LOCQUIC(R) PRIMER N 7649
Item No.: 21348
16. OTHER INFORMATION (continued)
Prepared By: Stephen Repetto
Title: Research Chemist, Environmental Health & Safety
Company: Loctite Corp., 1001 Tr Br Cr, Rocky Hill CT 06067
(24hr.) Phone: (860) 571-5100
Revision Date: January 22, 1996 Revision: 0004