LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 01 of 05 Removable Threadlocker 242 24221 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name: Removable Threadlocker 242 Item No.: 24221 Part of Kit: 00101 Product Type: Anaerobic 2. COMPOSITION, INFORMATION ON INGREDIENTS Ingredients CAS No. % Polyglycol dimethacrylate 25852-47-5 60-65 Polyglycol oleate 9004-96-0 25-30 SACCHARIN 81-07-2 3-5 CUMENE HYDROPEROXIDE* 80-15-9 1-3 Propylene glycol 57-55-6 1-3 SILICA, AMORPHOUS, FUMED, CRYSTALLINE-FREE 112945-52-5 1-3 N,N-Dialkyltoluidines 613-48-9 0.1-1 TITANIUM DIOXIDE 13463-67-7 0.1-0.5 * This component is listed as a SARA Section 313 Toxic Chemical. Ingredients which have exposure limits Exposure Limits (TWA) ACGIH OSHA OTHER Ingredients (TLV) (PEL) SILICA, AMORPHOUS, FUMED, CRYSTALLINE-FREE 10 mg/m3 TWA 6 mg/m3 TWA 3 mg/m3 TWA resp. dust TITANIUM DIOXIDE 10 mg/m3 dust 15 mg/m3 dust None 5 mg/m3 resp Exposure Limits (STEL) ACGIH OSHA Ingredients (TLV) (PEL) 3. HAZARDS IDENTIFICATION Toxicity: Mild eye irritant. Propylene glycol is a mild skin irritant. Primary Routes of Entry: Eye, skin contact. Signs and symptoms of Exposure: May cause dermatitis on prolonged contact in sensitive individuals Existing Conditions Aggravated by Exposure: Propylene glycol: dermatitis LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 02 of 05 Product Name: Removable Threadlocker 242 Item No.: 24221 3. HAZARDS IDENTIFICATION (continued) Literature Referenced Carcinogen Ingredients Target Organ and Other Health Effects NTP IARC OSHA Polyglycol dimethacrylate ALG IRR NO NO NO Polyglycol oleate IRR NO NO NO SACCHARIN No Data YES 2B NO CUMENE HYDROPEROXIDE ALG CNS COR IRR MUT NO NO NO Propylene glycol IRR NO NO NO SILICA, AMORPHOUS, FUMED, CRYSTALLINE-FREE NUI NO N/A NO N,N-Dialkyltoluidines No Data NO NO NO TITANIUM DIOXIDE AC4 IRR NUI NO NO NO ------------------------------------------------------------------------------- Abbreviations N/A Not Applicable 2B Possibly carcinogenic to humans AC4 ACGIH-Unclassifiable as human carc. ALG Allergen CNS Central nervous system COR Corrosive IRR Irritant MUT Mutagen NUI Nuisance dust 4. FIRST AID MEASURES Ingestion: Do not induce vomiting. Keep individual calm. Obtain medical attention Inhalation: Does not apply Skin Contact: Wash thoroughly with soap and water Eye Contact: Flush at least 15 minutes with water. Obtain medical attention. 5. FIRE FIGHTING MEASURES Flash Point: More than 200F Method: Tag Closed Cup Recommended Extinguishing Agents: Carbon dioxide, foam, dry chemical Hazardous Products formed by Fire or Thermal Decomp Irritating organic vapors; oxides of carbon. Unusual Fire or Explosion Hazards: None Explosive Limits: (% by volume in air)Lower Propylene glycol: 2.6% (% by volume in air)Upper Propylene glycol: 12.5% LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 03 of 05 Product Name: Removable Threadlocker 242 Item No.: 24221 6. ACCIDENTAL RELEASE MEASURES Steps to be taken in case of spill or leak: Soak up in an inert absorbant. Store in a partly filled, closed container until disposal. 7. HANDLING AND STORAGE Safe Storage: Store below 100F (Contact Loctite Customer Service 1-800-243-4874 for shelf Life information) Handling: Avoid prolonged skin contact. Keep away from eyes. 8. EXPOSURE CONTROLS, PERSONAL PROTECTION Eyes: Safety glasses or goggles. Skin: Neoprene, rubber, or butyl rubber gloves. Ventilation: Does not apply See Section 2 for Exposure Limits. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Blue liquid Odor: Mild Boiling Point: More than 300F pH: Does not apply Solubility in Water: Slight Specific Gravity 1.1 at 75F Volatile Organic Compound (EPA Method 24) 13.3%; 146 grams per liter Vapor Pressure: Less than 5mm at 80F Vapor Density: Not available Evaporation Rate (Ether = 1) Not available 10. STABILITY AND REACTIVITY Stability: Stable Hazardous Polymerization: Will not occur Incompatibility: Strong oxidizers, free radical initiators, inert gases. Conditions to Avoid: Not available Hazardous Decomposition Products (non-thermal): None 11. TOXICOLOGICAL INFORMATION Oral LD50 more than 10000 mg/kg. Dermal LD50 more than 5000 mg.kg. LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 04 of 05 Product Name: Removable Threadlocker 242 Item No.: 24221 12. ECOLOGICAL INFORMATION No data available 13. DISPOSAL CONSIDERATIONS Recommended methods of disposal: Incinerate following EPA and local regulations. EPA Hazardous Waste Number NH - Not a RCRA Hazardous Waste Material 14. TRANSPORTATION INFORMATION DOT (49 CFR 172) Domestic Ground Transport Proper Shipping Name: Unrestricted Hazard Class or Division: Unrestricted Identification Number: None Marine Pollutant: None IATA Proper Shipping Name: Unrestricted Class or Division: Unrestricted UN or ID Number: None 15. REGULATORY INFORMATION CA Proposition 65: This product contains Saccharin. No prop65 hazard warning is necessary if this product is used as reasonably anticipated. 16. OTHER INFORMATION Estimated NFPA(R) Code: Health Hazard: 1 Fire Hazard: 1 Reactivity Hazard: 1 Specific Hazard: Does not apply Estimated HMIS(R) Code: Health Hazard: 1* Flammability Hazard: 1 Reactivity Hazards: 1 Personal Protection: See Section 8. NFPA is a registered trademark of the National Fire Protection Assn. HMIS is a registered trademark of the National Paint and Coatings Assn. Prepared By: Stephen Repetto Title: Research Chemist, Health and Safety LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 05 of 05 Product Name: Removable Threadlocker 242 Item No.: 24221 16. OTHER INFORMATION (continued) Company: Loctite Corporation 1001 Trout Brook Crossing, Rocky HIll CT 06067 (24hr.) Phone: (860) 571-5100 Revision Date: April 15, 1997 Revision: 0031 LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 01 of 05 Permanent Threadlocker 262 26221 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name: Permanent Threadlocker 262 Item No.: 26221 Part of Kit: 00101 Product Type: Anaerobic 2. COMPOSITION, INFORMATION ON INGREDIENTS Ingredients CAS No. % Polyglycol dimethacrylate 25852-47-5 65-70 Bisphenol A fumarate resin 39382-25-7 20-25 CUMENE HYDROPEROXIDE* 80-15-9 1-3 Poly(ethylene) 9002-88-4 1-3 SACCHARIN 81-07-2 1-3 N,N-Dialkyltoluidines 613-48-9 0.1-1 SILICA, AMORPHOUS, FUMED, CRYSTALLINE-FREE 112945-52-5 0.1-1 * This component is listed as a SARA Section 313 Toxic Chemical. Ingredients which have exposure limits Exposure Limits (TWA) ACGIH OSHA OTHER Ingredients (TLV) (PEL) SILICA, AMORPHOUS, FUMED, CRYSTALLINE-FREE 10 mg/m3 TWA 6 mg/m3 TWA 3 mg/m3 TWA resp. dust Exposure Limits (STEL) ACGIH OSHA Ingredients (TLV) (PEL) 3. HAZARDS IDENTIFICATION Toxicity: Mild eye irritant. Oral LD50 more than 10,000 mg/kg. Dermal LD50 more than 5000 mg/kg. Primary Routes of Entry: Eyes, skin Signs and symptoms of Exposure: May cause dermatitis on prolonged contact in sensitive individuals Existing Conditions Aggravated by Exposure: None known LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 02 of 05 Product Name: Permanent Threadlocker 262 Item No.: 26221 3. HAZARDS IDENTIFICATION (continued) Literature Referenced Carcinogen Ingredients Target Organ and Other Health Effects NTP IARC OSHA Polyglycol dimethacrylate ALG IRR NO NO NO Bisphenol A fumarate resin ALG IRR NO NO NO CUMENE HYDROPEROXIDE ALG CNS COR IRR MUT NO NO NO Poly(ethylene) No Data NO N/A NO SACCHARIN No Data YES 2B NO N,N-Dialkyltoluidines No Data NO NO NO SILICA, AMORPHOUS, FUMED, CRYSTALLINE-FREE NUI NO N/A NO ------------------------------------------------------------------------------- Abbreviations N/A Not Applicable 2B Possibly carcinogenic to humans ALG Allergen CNS Central nervous system COR Corrosive IRR Irritant MUT Mutagen NUI Nuisance dust 4. FIRST AID MEASURES Ingestion: Do not induce vomiting. Keep individual calm. Obtain medical attention Inhalation: Does not apply Skin Contact: Wash thoroughly with soap and water Eye Contact: Flush at least 15 minutes with water. Obtain medical attention. 5. FIRE FIGHTING MEASURES Flash Point: More than 200F Method: Tag Closed Cup Recommended Extinguishing Agents: Carbon dioxide, foam, dry chemical Hazardous Products formed by Fire or Thermal Decomp Irritating organic vapors Unusual Fire or Explosion Hazards: None Explosive Limits: (% by volume in air)Lower Not available (% by volume in air)Upper Not available LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 03 of 05 Product Name: Permanent Threadlocker 262 Item No.: 26221 6. ACCIDENTAL RELEASE MEASURES Steps to be taken in case of spill or leak: Soak up in an inert absorbent. Store in a partly filled, closed container until disposal. 7. HANDLING AND STORAGE Safe Storage: Store below 100F (Contact Loctite Customer Service 1-800-243-4874 for shelf Life information) Handling: Avoid prolonged skin contact. Keep away from eyes. 8. EXPOSURE CONTROLS, PERSONAL PROTECTION Eyes: Safety glasses or goggles. Skin: Neoprene, rubber, or butyl rubber gloves. Ventilation: Does not apply See Section 2 for Exposure Limits. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Red liquid Odor: Mild Boiling Point: More than 300F pH: Does not apply Solubility in Water: Slight Specific Gravity 1.05 at 80F Volatile Organic Compound (EPA Method 24) 13.5%; 141.75 g/l Vapor Pressure: Less than 5mm at 80F Vapor Density: Not available Evaporation Rate (Ether = 1) Not available 10. STABILITY AND REACTIVITY Stability: Stable Hazardous Polymerization: Will not occur Incompatibility: None Conditions to Avoid: Not available Hazardous Decomposition Products (non-thermal): None 11. TOXICOLOGICAL INFORMATION See Section 3. LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 04 of 05 Product Name: Permanent Threadlocker 262 Item No.: 26221 12. ECOLOGICAL INFORMATION No data available 13. DISPOSAL CONSIDERATIONS Recommended methods of disposal: Incinerate following EPA and local regulations. EPA Hazardous Waste Number NH - Not a RCRA Hazardous Waste Material 14. TRANSPORTATION INFORMATION DOT (49 CFR 172) Domestic Ground Transport Proper Shipping Name: Unrestricted Hazard Class or Division: Unrestricted Identification Number: None Marine Pollutant: None IATA Proper Shipping Name: Unrestricted Class or Division: Unrestricted UN or ID Number: None 15. REGULATORY INFORMATION CA Proposition 65: This product contains Saccharin. No prop65 hazard warning is necessary if this product is used as reasonably anticipated. 16. OTHER INFORMATION Estimated NFPA(R) Code: Health Hazard: 1 Fire Hazard: 1 Reactivity Hazard: 1 Specific Hazard: Does not apply Estimated HMIS(R) Code: Health Hazard: 1 Flammability Hazard: 1 Reactivity Hazards: 1 Personal Protection: See Section 8. NFPA is a registered trademark of the National Fire Protection Assn. HMIS is a registered trademark of the National Paint and Coatings Assn. Prepared By: Stephen Repetto Title: Research Chemist, Environmental Health & Safety LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 05 of 05 Product Name: Permanent Threadlocker 262 Item No.: 26221 16. OTHER INFORMATION (continued) Company: Loctite Corp., 1001 Tr Br Cr, Rocky Hill CT 06067 (24hr.) Phone: (860) 571-5100 Revision Date: January 22, 1996 Revision: 0028 LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 01 of 07 Prism(R) 454 Surf-Insensit Gel Inst Adh 45404 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name: Prism(R) 454 Surf-Insensit Gel Inst Adh Item No.: 45404 Part of Kit: 00101 Product Type: Cyanoacrylate ester 2. COMPOSITION, INFORMATION ON INGREDIENTS Ingredients CAS No. % Ethyl cyanoacrylate 7085-85-0 85-90 Poly (methyl methacrylate) 9011-14-7 5-10 SILICA, AMORPHOUS, FUMED, CRYSTALLINE-FREE 112945-52-5 5-10 HYDROQUINONE 123-31-9 0.1-0.5 Ingredients which have exposure limits Exposure Limits (TWA) ACGIH OSHA OTHER Ingredients (TLV) (PEL) Ethyl cyanoacrylate None None 2 ppm TWA 9.1 mg/m3 SILICA, AMORPHOUS, FUMED, CRYSTALLINE-FREE 10 mg/m3 TWA 6 mg/m3 TWA 3 mg/m3 TWA resp. dust HYDROQUINONE 2 mg/m3 TWA 2 mg/m3 TWA 2 mg/m3 TWA 4 mg/m3 STEL Exposure Limits (STEL) ACGIH OSHA Ingredients (TLV) (PEL) Ethyl cyanoacrylate (4 ppm) (4 ppm) (18 mg/m3) (16 mg/m3) 3. HAZARDS IDENTIFICATION Toxicity: Skin contact may cause burns. Bonds skin rapidly and strongly. Skin and eye irritant. Estimated oral LD50 more than 5000 mg per kg. Estimated dermal LD50 more than 2000 mg per kg. Primary Routes of Entry: None known Signs and symptoms of Exposure: Vapor is irritating to eyes and mucous membranes above TLV. Prolonged and repeated overexposure to vapors may produce symptoms of non-allergic asthma in sensitive individuals. LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 02 of 07 Product Name: Prism(R) 454 Surf-Insensit Gel Inst Adh Item No.: 45404 3. HAZARDS IDENTIFICATION (continued) Existing Conditions Aggravated by Exposure: None known Literature Referenced Carcinogen Ingredients Target Organ and Other Health Effects NTP IARC OSHA Ethyl cyanoacrylate ALG IRR RES NO NO NO Poly (methyl methacrylate) IRR NO N/A NO SILICA, AMORPHOUS, FUMED, CRYSTALLINE-FREE NUI NO N/A NO HYDROQUINONE AC3 BLO BNM CNS EYE IMM IRR MUT NO N/A NO SKI ------------------------------------------------------------------------------- Abbreviations N/A Not Applicable AC3 ACGIH animal carcinogen. ALG Allergen BLO Blood BNM Bone Marrow CNS Central nervous system EYE Eyes IMM Immune system IRR Irritant MUT Mutagen NUI Nuisance dust RES Respiratory SKI Skin 4. FIRST AID MEASURES Ingestion: Ingestion is not likely. See supplemental page for emergency procedures. Inhalation: Remove to fresh air. If symptoms persist, obtain medical attention. Skin Contact: Soak in warm water. See supplemental page for emergency procedures. Eye Contact: Flush with water. See supplemental page for emergency procedures. 5. FIRE FIGHTING MEASURES Flash Point: 150 - 200F Method: Tag Closed Cup Recommended Extinguishing Agents: Carbon dioxide, foam, dry chemical Hazardous Products formed by Fire or Thermal Decomp Irritating organic vapors Unusual Fire or Explosion Hazards: None Explosive Limits: (% by volume in air)Lower Not available LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 03 of 07 Product Name: Prism(R) 454 Surf-Insensit Gel Inst Adh Item No.: 45404 5. FIRE FIGHTING MEASURES (continued) (% by volume in air)Upper Not available 6. ACCIDENTAL RELEASE MEASURES Steps to be taken in case of spill or leak: Flood with water to polymerize. Soak up with an inert absorbent. 7. HANDLING AND STORAGE Safe Storage: Store at or below 75 deg. F (Contact Loctite Customer Service 1-800-243-4874 for shelf Life information) Handling: Avoid contact with skin and eyes. Avoid breathing vapor. 8. EXPOSURE CONTROLS, PERSONAL PROTECTION Eyes: Safety glasses or goggles. Skin: Nitrile or polyethylene gloves and aprons. Do not use cotton. See supplemental page for additional information. Ventilation: Positive down-draft exhaust ventilation should be provided to maintain vapor concentration below TLV See Section 2 for Exposure Limits. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Water white gel Odor: Sharp, irritating Boiling Point: More than 300F pH: Does not apply Solubility in Water: Polymerized by water Specific Gravity 1.05 Volatile Organic Compound (EPA Method 24) 85.4%; 897 grams per liter Vapor Pressure: Less than 0.2 mm Vapor Density: Approximately 3 Evaporation Rate (Ether = 1) Not available 10. STABILITY AND REACTIVITY Stability: Stable Hazardous Polymerization: Will not occur Incompatibility: Polymerized by contact with water, alcohols, amines, alkalies. Conditions to Avoid: Not available LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 04 of 07 Product Name: Prism(R) 454 Surf-Insensit Gel Inst Adh Item No.: 45404 10. STABILITY AND REACTIVITY (continued) Hazardous Decomposition Products (non-thermal): None 11. TOXICOLOGICAL INFORMATION See Section 3. 12. ECOLOGICAL INFORMATION No data available 13. DISPOSAL CONSIDERATIONS Recommended methods of disposal: Polymerize as above. Incinerate following EPA and local regulations. EPA Hazardous Waste Number NH - Not a RCRA Hazardous Waste Material 14. TRANSPORTATION INFORMATION DOT (49 CFR 172) Domestic Ground Transport Proper Shipping Name: Unrestricted (Not more than 450 liters); Combustible liquids, n.o.s. (Cyanoacrylate ester) (More than 450 liters) Hazard Class or Division: Unrestricted (Not more than 450 liters) Combustible liquid (More than 450 liters) Identification Number: None (Not more than 450 liters); NA 1993 (More than 450 liters) Marine Pollutant: None IATA Proper Shipping Name: Unrestricted (Not more than one pint); Other regulated substances (More than one pint) Class or Division: Unrestricted (Not more than one pint); Class 9 (More than one pint) UN or ID Number: None (Not more than one pint) ID 8027 (More than one pint) 15. REGULATORY INFORMATION CA Proposition 65: No California Proposition 65 chemicals are known to be present. LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 05 of 07 Product Name: Prism(R) 454 Surf-Insensit Gel Inst Adh Item No.: 45404 16. OTHER INFORMATION Estimated NFPA(R) Code: Health Hazard: 2 Fire Hazard: 2 Reactivity Hazard: 1 Specific Hazard: Does not apply Estimated HMIS(R) Code: Health Hazard: 2 Flammability Hazard: 2 Reactivity Hazards: 1 Personal Protection: See Section 8. NFPA is a registered trademark of the National Fire Protection Assn. HMIS is a registered trademark of the National Paint and Coatings Assn. Prepared By: Stephen Repetto Title: Research Chemist, Environmental Health & Safety Company: Loctite Corp., 1001 Tr Br Cr, Rocky Hill CT 06067 (24hr.) Phone: (860) 571-5100 Revision Date: April 15, 1997 Revision: 0029 LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 06 of 07 Product Name: Prism(R) 454 Surf-Insensit Gel Inst Adh Item No.: 45404 Supplement INFORMATION FOR FIRST AID AND CASUALTY ON TREATMENT FOR ADHESION OF HUMAN SKIN TO ITSELF IF CAUSED BY CYANOACRYLATE ADHESIVES Cyanoacrylate adhesive is a very fast setting and strong adhesive. It bonds human tissue including skin in seconds. Experience has shown that accidents due to cyanoacrylates are handled best by passive, nonsurgical first aid. Treatment of specific types of accidents are given below. SKIN CONTACT Remove excess adhesive. Soak in warm, soapy water. The adhesive will come loose from the skin in several hours. Cured adhesive does not present a health hazard even when bonded to the skin. Avoid contact with clothes, fabrics, rags, or tissue. Contact with these materials may cause polymerization. The polymerization of large amounts of adhesive will generate heat causing smoke, skin burns, and strong, irritating vapors. Wear nitrile or polyethylene gloves and apron when handling large amounts of adhesive. SKIN ADHESION First immerse the bonded surfaces in warm, soapy water. Peel or roll the surfaces apart with the aid of a blunt edge, e.g. a spatula or a teaspoon handle; then remove adhesive from the skin with soap and water. Do not try to pull surfaces apart with a direct opposing action. EYELID TO EYELID OR EYEBALL ADHESION In the event that eyelids are stuck together or bonded to the eyeball, wash thoroughly with warm water and apply a gauze patch. The eye will open without further action, typically in 1-4 days. There will be no residual damage. Do not try to open the eyes by manipulation. ADHESIVE ON THE EYEBALL Cyanoacrylate introduced into the eyes will attach itself to the eye protein and will disassociate from it over intermittent periods, generally covering several hours. This will cause periods of weeping until clearance is achieved. During the period of contamination, double vision may be experienced together with a lachrymatory effect, and it is important to understand the cause and realize that disassociation will normally occur within a matter of hours, even with gross contamination. MOUTH If lips are accidentally stuck together, apply lots of warm water to the lips and encourage maximum wetting and pressure from saliva inside the mouth. Peel or roll lips apart. Do not try to pull the lips LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 07 of 07 Product Name: Prism(R) 454 Surf-Insensit Gel Inst Adh Item No.: 45404 Supplement with direct opposing action. It is almost impossible to swallow cyanoacrylate. The adhesive solidifies and adheres in the mouth. Saliva will lift the adhesive in one half to two days. In case a lump forms in the mouth, position the patient to prevent ingestion of the lump when it detaches. BURNS Cyanoacrylates give off heat on solidification. In rare cases a large drop will increase in temperature enough to cause a burn. Burns should be treated normally after the lump of cyanoacrylate is released from the tissue as described above. SURGERY It should never be necessary to use such a drastic method to separate accidentally bonded skin. LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 01 of 05 Gasket Eliminator(R) 518 Inst Seal/Flange Sealant 51831 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name: Gasket Eliminator(R) 518 Inst Seal/Flange Sealant Item No.: 51831 Part of Kit: 00101 Product Type: Anaerobic 2. COMPOSITION, INFORMATION ON INGREDIENTS Ingredients CAS No. % Polyurethane methacrylate Proprietary 70-75 Polyglycol dimethacrylate 25852-47-5 5-10 SILICA, AMORPHOUS, FUMED, CRYSTALLINE-FREE 112945-52-5 5-10 ACRYLIC ACID* 79-10-7 5-7 CUMENE HYDROPEROXIDE* 80-15-9 1-3 ETHYLENE GLYCOL* 107-21-1 1-3 1-Acetyl-2-phenylhydrazine 114-83-0 0.1-1 SACCHARIN 81-07-2 0.1-1 * This component is listed as a SARA Section 313 Toxic Chemical. Ingredients which have exposure limits Exposure Limits (TWA) ACGIH OSHA OTHER Ingredients (TLV) (PEL) SILICA, AMORPHOUS, FUMED, CRYSTALLINE-FREE 10 mg/m3 TWA 6 mg/m3 TWA 3 mg/m3 TWA resp. dust ACRYLIC ACID 2 ppm TWA skin 10 ppm TWA skin 1 ppm TWA skin 5.9 mg/m3 skin 30 mg/m3 skin 3 ppm STEL skin ETHYLENE GLYCOL None 50 ppm ceiling None 125mg/m3ceiling Exposure Limits (STEL) ACGIH OSHA Ingredients (TLV) (PEL) ETHYLENE GLYCOL 39.4ppm ceil ar None 100mg/m3 ceil a 3. HAZARDS IDENTIFICATION Toxicity: Liquid is an eye and skin irritant. Vapors may irritate eye, nose and throat. Estimated oral LD50 more than 5000 mg/kg. Estimated dermal LD50 more than 2000 mg/kg. Primary Routes of Entry: None known LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 02 of 05 Product Name: Gasket Eliminator(R) 518 Inst Seal/Flange Sealant Item No.: 51831 3. HAZARDS IDENTIFICATION (continued) Signs and symptoms of Exposure: Irritation of eyes, skin , nose or throat. May cause dermatitis on,prolonged contact in sensitive individuals. Existing Conditions Aggravated by Exposure: Acrylic acid: Upper respiratory and lung diseases. Literature Referenced Carcinogen Ingredients Target Organ and Other Health Effects NTP IARC OSHA Polyurethane methacrylate No Data NO NO NO Polyglycol dimethacrylate ALG IRR NO NO NO SILICA, AMORPHOUS, FUMED, CRYSTALLINE-FREE NUI NO N/A NO ACRYLIC ACID AC4 ALG COR IRR NO N/A NO CUMENE HYDROPEROXIDE ALG CNS COR IRR MUT NO NO NO ETHYLENE GLYCOL AC4 CNS DEV IRR KID MET NO NO NO 1-Acetyl-2-phenylhydrazine ALG NO NO NO SACCHARIN No Data YES 2B NO ------------------------------------------------------------------------------- Abbreviations N/A Not Applicable 2B Possibly carcinogenic to humans AC4 ACGIH-Unclassifiable as human carc. ALG Allergen CNS Central nervous system COR Corrosive DEV Developmental IRR Irritant KID Kidney MET Metabolic MUT Mutagen NUI Nuisance dust 4. FIRST AID MEASURES Ingestion: Do not induce vomiting. Keep individual calm. Obtain medical attention. Inhalation: Remove to fresh air. If symptoms persist, obtain medical attention. Skin Contact: Wash thoroughly with soap and water Eye Contact: Flush at least 15 minutes with water. Obtain medical attention. 5. FIRE FIGHTING MEASURES Flash Point: More than 200F Method: Tag Closed Cup Recommended Extinguishing Agents: Carbon dioxide, foam, dry chemical LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 03 of 05 Product Name: Gasket Eliminator(R) 518 Inst Seal/Flange Sealant Item No.: 51831 5. FIRE FIGHTING MEASURES (continued) Hazardous Products formed by Fire or Thermal Decomp Irritating organic vapors. Unusual Fire or Explosion Hazards: None Explosive Limits: (% by volume in air)Lower 2.0% Acrylic acid (% by volume in air)Upper 8.0% Acrylic acid 6. ACCIDENTAL RELEASE MEASURES Steps to be taken in case of spill or leak: Scrape up as much as possible and store in a partly filled, closed container until disposal. Residues may be cleaned up with solvent. 7. HANDLING AND STORAGE Safe Storage: Store below 100 deg. F (Contact Loctite Customer Service 1-800-243-4874 for shelf Life information) Handling: Avoid skin and eye contact. Avoid breathing vapor 8. EXPOSURE CONTROLS, PERSONAL PROTECTION Eyes: Safety glasses or goggles. Skin: Rubber or plastic gloves. Ventilation: Sufficient to maintain vapor concentration below TLV See Section 2 for Exposure Limits. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Red gel Odor: Mild Boiling Point: More than 300F pH: Does not apply Solubility in Water: Low Specific Gravity 1.1 at 80F Volatile Organic Compound (EPA Method 24) 13.0%; 143 grams per liter Vapor Pressure: Less than 5mm at 80F Vapor Density: Not available Evaporation Rate (Ether = 1) Not available LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 04 of 05 Product Name: Gasket Eliminator(R) 518 Inst Seal/Flange Sealant Item No.: 51831 10. STABILITY AND REACTIVITY Stability: Stable Hazardous Polymerization: Will not occur Incompatibility: None Conditions to Avoid: Not available Hazardous Decomposition Products (non-thermal): None 11. TOXICOLOGICAL INFORMATION See Section 3. 12. ECOLOGICAL INFORMATION No data available 13. DISPOSAL CONSIDERATIONS Recommended methods of disposal: Incinerate following EPA and local regulations. EPA Hazardous Waste Number NH - Not a RCRA Hazardous Waste Material 14. TRANSPORTATION INFORMATION DOT (49 CFR 172) Domestic Ground Transport Proper Shipping Name: Unrestricted Hazard Class or Division: Unrestricted Identification Number: None Marine Pollutant: None IATA Proper Shipping Name: Unrestricted Class or Division: Unrestricted UN or ID Number: None 15. REGULATORY INFORMATION CA Proposition 65: WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. Ethylene Oxide This product contains Saccharin. No Prop65 hazard warning is necessary if this product is used as reasonably anticipated. LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 05 of 05 Product Name: Gasket Eliminator(R) 518 Inst Seal/Flange Sealant Item No.: 51831 16. OTHER INFORMATION Estimated NFPA(R) Code: Health Hazard: 2 Fire Hazard: 1 Reactivity Hazard: 1 Specific Hazard: Does not apply Estimated HMIS(R) Code: Health Hazard: 2 Flammability Hazard: 1 Reactivity Hazards: 1 Personal Protection: See Section 8. NFPA is a registered trademark of the National Fire Protection Assn. HMIS is a registered trademark of the National Paint and Coatings Assn. Prepared By: Stephen Repetto Title: Research Chemist, Environmental Health & Safety Company: Loctite Corp., 1001 Tr Br Cr, Rocky Hill CT 06067 (24hr.) Phone: (860) 571-5100 Revision Date: April 15, 1997 Revision: 0031 LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 01 of 05 PST(R) Pipe Sealant 565 Thread Sealant 56531 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name: PST(R) Pipe Sealant 565 Thread Sealant Item No.: 56531 Part of Kit: 00101 Product Type: Anaerobic 2. COMPOSITION, INFORMATION ON INGREDIENTS Ingredients CAS No. % Polyglycol dimethacrylate 25852-47-5 35-40 Polymeric plasticizer 68332-62-7 25-30 Cellulose ester 9004-36-8 15-20 Poly(tetrafluoroethylene) 9002-84-0 5-10 SILICA, AMORPHOUS, FUMED, CRYSTALLINE-FREE 112945-52-5 3-5 TITANIUM DIOXIDE 13463-67-7 3-5 CUMENE HYDROPEROXIDE* 80-15-9 1-3 SACCHARIN 81-07-2 1-3 N,N-Dialkyltoluidines 613-48-9 0.1-1 Poly(ethylene) 9002-88-4 0.1-0.5 * This component is listed as a SARA Section 313 Toxic Chemical. Ingredients which have exposure limits Exposure Limits (TWA) ACGIH OSHA OTHER Ingredients (TLV) (PEL) SILICA, AMORPHOUS, FUMED, CRYSTALLINE-FREE 10 mg/m3 TWA 6 mg/m3 TWA 3 mg/m3 TWA resp. dust TITANIUM DIOXIDE 10 mg/m3 dust 15 mg/m3 dust None 5 mg/m3 resp Exposure Limits (STEL) ACGIH OSHA Ingredients (TLV) (PEL) 3. HAZARDS IDENTIFICATION Toxicity: Moderate eye irritant. Estimated Oral LD50 greater than 5,000 mg/kg. Estimated Dermal LD50 greater than 2,000 mg/kg. Primary Routes of Entry: None known Signs and symptoms of Exposure: May cause dermatitis on prolonged contact in sensitive individuals LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 02 of 05 Product Name: PST(R) Pipe Sealant 565 Thread Sealant Item No.: 56531 3. HAZARDS IDENTIFICATION (continued) Existing Conditions Aggravated by Exposure: None known Literature Referenced Carcinogen Ingredients Target Organ and Other Health Effects NTP IARC OSHA Polyglycol dimethacrylate ALG IRR NO NO NO Polymeric plasticizer No Data NO NO NO Cellulose ester No Data NO NO NO Poly(tetrafluoroethylene) No Data NO N/A NO SILICA, AMORPHOUS, FUMED, CRYSTALLINE-FREE NUI NO N/A NO TITANIUM DIOXIDE AC4 IRR NUI NO NO NO CUMENE HYDROPEROXIDE ALG CNS COR IRR MUT NO NO NO SACCHARIN No Data YES 2B NO N,N-Dialkyltoluidines No Data NO NO NO Poly(ethylene) No Data NO N/A NO ------------------------------------------------------------------------------- Abbreviations N/A Not Applicable 2B Possibly carcinogenic to humans AC4 ACGIH-Unclassifiable as human carc. ALG Allergen CNS Central nervous system COR Corrosive IRR Irritant MUT Mutagen NUI Nuisance dust 4. FIRST AID MEASURES Ingestion: Do not induce vomiting. Keep individual calm. Obtain medical attention. Inhalation: Does not apply Skin Contact: Wash with soap and water. Eye Contact: Flush at least 15 minutes with water. Obtain medical attention. 5. FIRE FIGHTING MEASURES Flash Point: More than 200F Method: Tag Closed Cup Recommended Extinguishing Agents: Carbon dioxide, foam, dry chemical Hazardous Products formed by Fire or Thermal Decomp Irritating organic vapors. Toxic fluorides. Unusual Fire or Explosion Hazards: None Explosive Limits: LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 03 of 05 Product Name: PST(R) Pipe Sealant 565 Thread Sealant Item No.: 56531 5. FIRE FIGHTING MEASURES (continued) (% by volume in air)Lower Not available (% by volume in air)Upper Not available 6. ACCIDENTAL RELEASE MEASURES Steps to be taken in case of spill or leak: Soak up in an inert absorbent. Store in a partly filled, closed container until disposal. 7. HANDLING AND STORAGE Safe Storage: Store below 100F (Contact Loctite Customer Service 1-800-243-4874 for shelf Life information) Handling: Avoid prolonged skin contact. Keep away from eyes. 8. EXPOSURE CONTROLS, PERSONAL PROTECTION Eyes: Safety glasses or goggles. Skin: Rubber or plastic gloves. Ventilation: Does not apply See Section 2 for Exposure Limits. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: White paste Odor: Mild Boiling Point: More than 300F pH: Does not apply Solubility in Water: Slight Specific Gravity 1.1 at 80F Volatile Organic Compound (EPA Method 24) 7.9%; 87 grams per liter Vapor Pressure: Less than 5mm at 80F Vapor Density: Not available Evaporation Rate (Ether = 1) Not available 10. STABILITY AND REACTIVITY Stability: Stable Hazardous Polymerization: Will not occur Incompatibility: None Conditions to Avoid: Not available Hazardous Decomposition Products (non-thermal): Irritating organic and inorganic vapors. Toxic fluorides. LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 04 of 05 Product Name: PST(R) Pipe Sealant 565 Thread Sealant Item No.: 56531 11. TOXICOLOGICAL INFORMATION See Section 3. 12. ECOLOGICAL INFORMATION No data available 13. DISPOSAL CONSIDERATIONS Recommended methods of disposal: Incinerate or dispose of in approved landfill for non-RCRA materials following local, state and federal regulations. EPA Hazardous Waste Number NH - Not a RCRA Hazardous Waste Material 14. TRANSPORTATION INFORMATION DOT (49 CFR 172) Domestic Ground Transport Proper Shipping Name: Unrestricted Hazard Class or Division: Unrestricted Identification Number: None Marine Pollutant: None IATA Proper Shipping Name: Unrestricted Class or Division: Unrestricted UN or ID Number: None 15. REGULATORY INFORMATION CA Proposition 65: This product contains Saccharin. No prop65 hazard warning is necessary if this product is used as reasonably anticipated. 16. OTHER INFORMATION Estimated NFPA(R) Code: Health Hazard: 1 Fire Hazard: 1 Reactivity Hazard: 1 Specific Hazard: Does not apply Estimated HMIS(R) Code: Health Hazard: 1 Flammability Hazard: 1 Reactivity Hazards: 1 Personal Protection: See Section 8. LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 05 of 05 Product Name: PST(R) Pipe Sealant 565 Thread Sealant Item No.: 56531 16. OTHER INFORMATION (continued) NFPA is a registered trademark of the National Fire Protection Assn. HMIS is a registered trademark of the National Paint and Coatings Assn. Prepared By: Stephen Repetto Title: Research Chemist, Health and Safety Company: Loctite Corp., 1001 Tr Br Cr, Rocky Hill CT 06067 (24hr.) Phone: (860) 571-5100 Revision Date: April 15, 1997 Revision: 0029 LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 01 of 05 Superflex(R) Ultra-Blue(TM) Silicone 58730 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name: Superflex(R) Ultra-Blue(TM) Silicone Item No.: 58730 Part of Kit: 00101 Product Type: RTV Silicone 2. COMPOSITION, INFORMATION ON INGREDIENTS Ingredients CAS No. % Poly(dimethylsiloxane), hydroxy terminated 70131-67-8 35-40 Calcium carbonate 471-34-1 30-35 Poly(dimethylsiloxane), dimethyl 63148-62-9 15-20 Modified silicon dioxide 68611-44-9 5-10 Vinyl oximinosilane 2224-33-1 3-5 Substituted silane Proprietary 0.1-1 Methyl ethyl ketoxime Proprietary *** ***When this product is exposed to moisture, 5-10% methyl ethyl ketoxime may be formed. Ingredients which have exposure limits Exposure Limits (TWA) ACGIH OSHA OTHER Ingredients (TLV) (PEL) Calcium carbonate 10 mg/m3 dust 15 mg/m3 dust None 5 mg/m3 respir. Modified silicon dioxide 10 mg/m3 6 mg/m3 6 mg/m3 Methyl ethyl ketoxime None None 3 ppm TWA 10 ppm STEL Exposure Limits (STEL) ACGIH OSHA Ingredients (TLV) (PEL) 3. HAZARDS IDENTIFICATION Toxicity: Eye and skin irritant. Moderately toxic by ingestion. When heated to temperatures above 300F (150F) in the presence of air, this product can form formaldehyde vapors. Formaldehyde is a potential cancer hazard and a known skin and respiratory sensitizer. Vapors irritate eyes, nose and throat. LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 02 of 05 Product Name: Superflex(R) Ultra-Blue(TM) Silicone Item No.: 58730 3. HAZARDS IDENTIFICATION (continued) Safe handling conditions may be maintained by keeping vapor concentrations below the OSHA permissible limit for formaldehyde. Primary Routes of Entry: Skin absorbtion, ingestion, inhalation. Signs and symptoms of Exposure: Methyl ethyl ketoxime produced during cure is toxic and irritates eyes, nose and throat. Existing Conditions Aggravated by Exposure: Dermatitis Literature Referenced Carcinogen Ingredients Target Organ and Other Health Effects NTP IARC OSHA Poly(dimethylsiloxane), hydroxy terminated No Data NO NO NO Calcium carbonate NUI NO NO NO Poly(dimethylsiloxane), dimethyl IRR NO NO NO Modified silicon dioxide No Data NO NO NO Vinyl oximinosilane No Data NO NO NO Substituted silane No Data NO NO NO Methyl ethyl ketoxime ALG BLO CNS IRR NO NO NO ------------------------------------------------------------------------------- Abbreviations ALG Allergen BLO Blood CNS Central nervous system IRR Irritant NUI Nuisance dust 4. FIRST AID MEASURES Ingestion: Do not induce vomiting. Keep individual calm. Obtain medical attention Inhalation: Remove to fresh air. If symptoms persist, obtain medical attention. Skin Contact: Wipe off paste with paper towel or cloth. Wash thoroughly with soap and water Eye Contact: Flush at least 15 minutes with water. Obtain medical attention. 5. FIRE FIGHTING MEASURES Flash Point: More than 200F Method: Tag Closed Cup Recommended Extinguishing Agents: Carbon dioxide, foam, dry chemical LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 03 of 05 Product Name: Superflex(R) Ultra-Blue(TM) Silicone Item No.: 58730 5. FIRE FIGHTING MEASURES (continued) Hazardous Products formed by Fire or Thermal Decomp Formaldehyde, silica fume Unusual Fire or Explosion Hazards: None Explosive Limits: (% by volume in air)Lower Not available (% by volume in air)Upper Not available 6. ACCIDENTAL RELEASE MEASURES Steps to be taken in case of spill or leak: Wipe or scrape up spilled material. Maintain good ventilation for large spills. Place scrap material in a well ventilated area and allow to cure to rubber. 7. HANDLING AND STORAGE Safe Storage: Store in a dry area below 90F. Keep containers closed when not in use. (Contact Loctite Customer Service 1-800-243-4874 for shelf Life information) Handling: Avoid skin and eye contact. Avoid breathing vapor Do not wear contact lenses while applying material Vapor may be trapped under lens. 8. EXPOSURE CONTROLS, PERSONAL PROTECTION Eyes: Safety glasses or goggles. Skin: Rubber or plastic gloves. Ventilation: Provide local ventilation for prolonged use in a confined area. See Section 2 for Exposure Limits. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Blue paste Odor: Mild Boiling Point: Not Applicable, Polymeric pH: 7-8 Solubility in Water: Polymerized Specific Gravity 1.3 Volatile Organic Compound (EPA Method 24) 3.9%; 50.7 grams per liter Vapor Pressure: Less than 5mm at 70F Vapor Density: 3.0 LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 04 of 05 Product Name: Superflex(R) Ultra-Blue(TM) Silicone Item No.: 58730 9. PHYSICAL AND CHEMICAL PROPERTIES (continued) Evaporation Rate (Ether = 1) Not available 10. STABILITY AND REACTIVITY Stability: Stable Hazardous Polymerization: Will not occur Incompatibility: Strong oxidizers. Polymerized by contact with moisture. Conditions to Avoid: Not available Hazardous Decomposition Products (non-thermal): Methyl ethyl ketoxime 11. TOXICOLOGICAL INFORMATION See Section 3. 12. ECOLOGICAL INFORMATION No data available 13. DISPOSAL CONSIDERATIONS Recommended methods of disposal: Cured rubber can be incinerated following EPA and local regulations EPA Hazardous Waste Number NH - Not a RCRA Hazardous Waste Material 14. TRANSPORTATION INFORMATION DOT (49 CFR 172) Domestic Ground Transport Proper Shipping Name: Unrestricted Hazard Class or Division: Unrestricted Identification Number: None Marine Pollutant: None IATA Proper Shipping Name: Unrestricted Class or Division: Unrestricted UN or ID Number: None 15. REGULATORY INFORMATION CA Proposition 65: WARNING: This product contains chemicals known to the State of California to cause birth defects or other reproductive harm. LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 05 of 05 Product Name: Superflex(R) Ultra-Blue(TM) Silicone Item No.: 58730 15. REGULATORY INFORMATION (continued) traces of toluene 16. OTHER INFORMATION Estimated NFPA(R) Code: Health Hazard: 1 Fire Hazard: 1 Reactivity Hazard: 0 Specific Hazard: No water. Estimated HMIS(R) Code: Health Hazard: 1 Flammability Hazard: 1 Reactivity Hazards: 0 Personal Protection: See Section 8. NFPA is a registered trademark of the National Fire Protection Assn. HMIS is a registered trademark of the National Paint and Coatings Assn. Prepared By: Stephen Repetto Title: Research Chemist, Environmental Health & Safety Company: Loctite Corp., 1001 Tr Br Cr, Rocky Hill CT 06067 (24hr.) Phone: (860) 571-5100 Revision Date: January 22, 1996 Revision: 0031 LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 01 of 05 660 Quick Metal(R) Press Fit Repair Retaining Cmpd 66010 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name: 660 Quick Metal(R) Press Fit Repair Retaining Cmpd Item No.: 66010 Part of Kit: 00101 Product Type: Anaerobic 2. COMPOSITION, INFORMATION ON INGREDIENTS Ingredients CAS No. % Aromatic dimethacrylate ester 24448-20-2 40-45 Hydroxyalkyl methacrylate 27813-02-1 30-35 Bisphenol A fumarate resin 39382-25-7 5-10 SILICA, AMORPHOUS, FUMED, CRYSTALLINE-FREE 112945-52-5 5-10 Poly(vinyl acetate) 9003-20-7 3-5 CUMENE HYDROPEROXIDE* 80-15-9 1-3 METHYL ALCOHOL* 67-56-1 1-3 TITANIUM DIOXIDE 13463-67-7 1-3 1-Acetyl-2-phenylhydrazine 114-83-0 0.1-1 N,N-Dialkyltoluidines 613-48-9 0.1-1 MALEIC ACID 110-16-7 0.1-1 SACCHARIN 81-07-2 0.1-1 * This component is listed as a SARA Section 313 Toxic Chemical. Ingredients which have exposure limits Exposure Limits (TWA) ACGIH OSHA OTHER Ingredients (TLV) (PEL) Hydroxyalkyl methacrylate None None 3 ppm ceiling SILICA, AMORPHOUS, FUMED, CRYSTALLINE-FREE 10 mg/m3 TWA 6 mg/m3 TWA 3 mg/m3 TWA resp. dust METHYL ALCOHOL 200ppm TWA skin 200ppm TWA skin None 262 mg/m3 skin 262 mg/m3 skin TITANIUM DIOXIDE 10 mg/m3 dust 15 mg/m3 dust None 5 mg/m3 resp Exposure Limits (STEL) ACGIH OSHA Ingredients (TLV) (PEL) METHYL ALCOHOL 250 ppm skin 250 ppm skin 328 mg/m3 skin 325 mg/m3 skin LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 02 of 05 Product Name: 660 Quick Metal(R) Press Fit Repair Retaining Cmpd Item No.: 66010 3. HAZARDS IDENTIFICATION Toxicity: Severe eye irritant. Moderate skin irritant. Possible inhalation irritant. May be harmful if swallowed. May cause kidney or liver damage. Estimated oral LD50 more than 5000 mg/kg. Estimated dermal LD50 more than 2000 mg/kg. Primary Routes of Entry: Eye, skin, inhalation, ingestion. Signs and symptoms of Exposure: May cause severe dermatitis on prolonged contact in sensitive individuals. Existing Conditions Aggravated by Exposure: None known Literature Referenced Carcinogen Ingredients Target Organ and Other Health Effects NTP IARC OSHA Aromatic dimethacrylate ester ALG IRR NO NO NO Hydroxyalkyl methacrylate ALG IRR NO NO NO Bisphenol A fumarate resin ALG IRR NO NO NO SILICA, AMORPHOUS, FUMED, CRYSTALLINE-FREE NUI NO N/A NO Poly(vinyl acetate) No Data NO N/A NO CUMENE HYDROPEROXIDE ALG CNS COR IRR MUT NO NO NO METHYL ALCOHOL EYE IRR MET NER NO NO NO TITANIUM DIOXIDE AC4 IRR NUI NO NO NO 1-Acetyl-2-phenylhydrazine ALG NO NO NO N,N-Dialkyltoluidines No Data NO NO NO MALEIC ACID IRR NO NO NO SACCHARIN No Data YES 2B NO ------------------------------------------------------------------------------- Abbreviations N/A Not Applicable 2B Possibly carcinogenic to humans AC4 ACGIH-Unclassifiable as human carc. ALG Allergen CNS Central nervous system COR Corrosive EYE Eyes IRR Irritant MET Metabolic MUT Mutagen NER Nervous System NUI Nuisance dust 4. FIRST AID MEASURES Ingestion: Do not induce vomiting. Keep individual calm. Obtain medical attention Inhalation: Remove to fresh air. If symptoms persist, obtain medical attention. Skin Contact: Wash thoroughly with soap and water LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 03 of 05 Product Name: 660 Quick Metal(R) Press Fit Repair Retaining Cmpd Item No.: 66010 4. FIRST AID MEASURES (continued) Eye Contact: Flush at least 15 minutes with water. Obtain medical attention. 5. FIRE FIGHTING MEASURES Flash Point: More than 200F Method: Tag Closed Cup Recommended Extinguishing Agents: Carbon dioxide, foam, dry chemical Hazardous Products formed by Fire or Thermal Decomp Oxides of carbon Unusual Fire or Explosion Hazards: None Explosive Limits: (% by volume in air)Lower Methanol: 6% (% by volume in air)Upper Methanol: 36% 6. ACCIDENTAL RELEASE MEASURES Steps to be taken in case of spill or leak: Soak up in an inert absorbent. Store in a partly filled, closed container until disposal. 7. HANDLING AND STORAGE Safe Storage: Store below 100F (Contact Loctite Customer Service 1-800-243-4874 for shelf Life information) Handling: Avoid prolonged skin contact. Keep away from eyes. 8. EXPOSURE CONTROLS, PERSONAL PROTECTION Eyes: Safety glasses or goggles. Skin: Rubber or plastic gloves. Ventilation: Sufficient to maintain vapor concentration below TLV. See Section 2 for Exposure Limits. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Silver paste Odor: Mild Boiling Point: Greater than 300F pH: Does not apply Solubility in Water: Slight Specific Gravity 1.10 at 75F Volatile Organic Compound (EPA Method 24) 38.1%; 419 grams per liter LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 04 of 05 Product Name: 660 Quick Metal(R) Press Fit Repair Retaining Cmpd Item No.: 66010 9. PHYSICAL AND CHEMICAL PROPERTIES (continued) Vapor Pressure: Less than 5mm at 80F Vapor Density: Not available Evaporation Rate (Ether = 1) Not available 10. STABILITY AND REACTIVITY Stability: Stable Hazardous Polymerization: Hazardous polymerization may occur if over- catalyzed or insufficiently aerated after catalyzation. This polymerization is exothermic. Incompatibility: Reducing agents Conditions to Avoid: Not available Hazardous Decomposition Products (non-thermal): None 11. TOXICOLOGICAL INFORMATION See Section 3. 12. ECOLOGICAL INFORMATION No data available 13. DISPOSAL CONSIDERATIONS Recommended methods of disposal: Incinerate following EPA and local regulations. EPA Hazardous Waste Number NH - Not a RCRA Hazardous Waste Material 14. TRANSPORTATION INFORMATION DOT (49 CFR 172) Domestic Ground Transport Proper Shipping Name: Unrestricted Hazard Class or Division: Unrestricted Identification Number: None Marine Pollutant: None IATA Proper Shipping Name: Unrestricted Class or Division: Unrestricted UN or ID Number: None LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 05 of 05 Product Name: 660 Quick Metal(R) Press Fit Repair Retaining Cmpd Item No.: 66010 15. REGULATORY INFORMATION CA Proposition 65: This product contains Saccharin. No prop65 hazard warning is necessary if this product is used as reasonably anticipated. 16. OTHER INFORMATION Estimated NFPA(R) Code: Health Hazard: 1 Fire Hazard: 1 Reactivity Hazard: 1 Specific Hazard: Does not apply Estimated HMIS(R) Code: Health Hazard: 1 Flammability Hazard: 1 Reactivity Hazards: 1 Personal Protection: See Section 8. NFPA is a registered trademark of the National Fire Protection Assn. HMIS is a registered trademark of the National Paint and Coatings Assn. Prepared By: Stephen Repetto Title: Research Chemist, Environmental Health & Safety Company: Loctite Corp., 1001 Tr Br Cr, Rocky Hill CT 06067 (24hr.) Phone: (860) 571-5100 Revision Date: April 15, 1997 Revision: 0034 LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 01 of 05 LOCQUIC(R) PRIMER N 7649 21348 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name: LOCQUIC(R) PRIMER N 7649 Item No.: 21348 Part of Kit: 00101 Product Type: Aerosol accelerator 2. COMPOSITION, INFORMATION ON INGREDIENTS Ingredients CAS No. % ACETONE 67-64-1 75-80 ISOBUTANE 75-28-5 20-25 2-Ethylhexanoic acid 149-57-5 0.1-1 Organo-copper compound 22221-10-9 0.1-1 Trialkylammonium Carboxylate 58823-74-8 0.1-1 Ingredients which have exposure limits Exposure Limits (TWA) ACGIH OSHA OTHER Ingredients (TLV) (PEL) ACETONE 750 ppm TWA 750 ppm TWA None 1780 mg/m3 1800 mg/m3 Organo-copper compound Cu 0.2mg/m3fume Cu 0.1mg/m3 None Cu 1 mg/m3 dust Cu 1 mg/m3 dust Exposure Limits (STEL) ACGIH OSHA Ingredients (TLV) (PEL) ACETONE 1000 ppm 1000 ppm 2380 mg/m3 2400 mg/m3 3. HAZARDS IDENTIFICATION Toxicity: Harmful if inhaled or swallowed. Possible eye and respiratory irritant. Narcotic at high concentrations. Prolonged inhalation may cause headaches. Moderately toxic by ingestion Liquid may defat skin. Primary Routes of Entry: Inhalation, ingestion, contact. Signs and symptoms of Exposure: Vapors irritate eyes, nose and throat. Liquid is an eye irritant and may irritate skin. Existing Conditions Aggravated by Exposure: None known LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 02 of 05 Product Name: LOCQUIC(R) PRIMER N 7649 Item No.: 21348 3. HAZARDS IDENTIFICATION (continued) Literature Referenced Carcinogen Ingredients Target Organ and Other Health Effects NTP IARC OSHA ACETONE BLO CNS IRR NO NO NO ISOBUTANE CAR CNS LUN NO NO NO 2-Ethylhexanoic acid IRR NO NO NO Organo-copper compound No Data NO NO NO Trialkylammonium Carboxylate No Data NO NO NO ------------------------------------------------------------------------------- Abbreviations BLO Blood CAR Cardiac CNS Central nervous system IRR Irritant LUN Lung 4. FIRST AID MEASURES Ingestion: Give water to dilute. Do not induce vomiting. Keep individual calm. Obtain medical attention. Inhalation: Remove to fresh air. If symptoms persist, obtain medical attention. Skin Contact: Wash with soap and water. Eye Contact: Flush with water for at least 15 minutes. Obtain medical attention. 5. FIRE FIGHTING MEASURES Flash Point: Approximately -4F(Base) Method: Tag Closed Cup Recommended Extinguishing Agents: Carbon dioxide, foam, dry chemical Hazardous Products formed by Fire or Thermal Decomp Irritating organic vapors Unusual Fire or Explosion Hazards: Cans may burst in fires. Explosive Limits: (% by volume in air)Lower Acetone: 2.6% Isobutane: 1.8% (% by volume in air)Upper Acetone: 13% Isobutane: 8.4% 6. ACCIDENTAL RELEASE MEASURES Steps to be taken in case of spill or leak: Avoid flame and sparks. Maintain adequate ventilation. Soak up in an inert absorbent and LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 03 of 05 Product Name: LOCQUIC(R) PRIMER N 7649 Item No.: 21348 6. ACCIDENTAL RELEASE MEASURES (continued) store in a closed container until disposal. 7. HANDLING AND STORAGE Safe Storage: Store away from flame and sparks and below 120F (Contact Loctite Customer Service 1-800-243-4874 for shelf Life information) Handling: Avoid prolonged breathing of fumes. Avoid skin or eye contact. Do not use near heat, sparks, or open flame. 8. EXPOSURE CONTROLS, PERSONAL PROTECTION Eyes: Safety glasses or goggles. Skin: Rubber or plastic gloves. Ventilation: Sufficient to maintain vapor concentration below TLV. See Section 2 for Exposure Limits. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Green liquid (Base only) Odor: Acetone Boiling Point: 133F (Base only) pH: Does not apply Solubility in Water: Miscible Specific Gravity 0.7936 (Base only) Volatile Organic Compound (EPA Method 24) 1.48%;11.7 grams per liter of material (Base only) Vapor Pressure: Approximately 172 mm Hg at 68F (Base only) Vapor Density: Not available Evaporation Rate (Ether = 1) 1.9 (Base only) 10. STABILITY AND REACTIVITY Stability: Stable Hazardous Polymerization: Will not occur Incompatibility: Strong oxidizers, peroxides Conditions to Avoid: Not available Hazardous Decomposition Products (non-thermal): None 11. TOXICOLOGICAL INFORMATION See Section 3. LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 04 of 05 Product Name: LOCQUIC(R) PRIMER N 7649 Item No.: 21348 12. ECOLOGICAL INFORMATION No data available 13. DISPOSAL CONSIDERATIONS Recommended methods of disposal: Use disposal service licensed to handle flammable aerosols. EPA Hazardous Waste Number D001 - Hazardous waste per 40CFR 261.21 14. TRANSPORTATION INFORMATION DOT (49 CFR 172) Domestic Ground Transport Proper Shipping Name: Consumer Commodity Hazard Class or Division: ORM-D Identification Number: None Marine Pollutant: None IATA Proper Shipping Name: Aerosols, flammable, n.o.s. Class or Division: Division 2.1 UN or ID Number: UN 1950 15. REGULATORY INFORMATION CA Proposition 65: WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. Traces of lead and nickel 16. OTHER INFORMATION Estimated NFPA(R) Code: Health Hazard: 2 Fire Hazard: 4 Reactivity Hazard: 0 Specific Hazard: Does not apply Estimated HMIS(R) Code: Health Hazard: 2 Flammability Hazard: 4 Reactivity Hazards: 0 Personal Protection: See Section 8. NFPA is a registered trademark of the National Fire Protection Assn. HMIS is a registered trademark of the National Paint and Coatings Assn. LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 05 of 05 Product Name: LOCQUIC(R) PRIMER N 7649 Item No.: 21348 16. OTHER INFORMATION (continued) Prepared By: Stephen Repetto Title: Research Chemist, Environmental Health & Safety Company: Loctite Corp., 1001 Tr Br Cr, Rocky Hill CT 06067 (24hr.) Phone: (860) 571-5100 Revision Date: January 22, 1996 Revision: 0004