LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 01 of 05 Small Screw Threadlocker 222MS 22221 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name: Small Screw Threadlocker 222MS Item No.: 22221 Product Type: Anaerobic 2. COMPOSITION, INFORMATION ON INGREDIENTS Ingredients CAS No. % Polyglycol dimethacrylate 25852-47-5 50-55 Polyglycol oleate 9004-96-0 35-40 SACCHARIN 81-07-2 3-5 CUMENE HYDROPEROXIDE* 80-15-9 1-3 Propylene glycol 57-55-6 1-3 SILICA, AMORPHOUS, FUMED, CRYSTALLINE-FREE 112945-52-5 1-3 N,N-Dialkyltoluidines 613-48-9 0.1-1 TITANIUM DIOXIDE 13463-67-7 0.1-0.5 * This component is listed as a SARA Section 313 Toxic Chemical. Ingredients which have exposure limits Exposure Limits (TWA) ACGIH OSHA OTHER Ingredients (TLV) (PEL) SILICA, AMORPHOUS, FUMED, CRYSTALLINE-FREE 10 mg/m3 TWA 6 mg/m3 TWA 3 mg/m3 TWA resp. dust TITANIUM DIOXIDE 10 mg/m3 dust 15 mg/m3 dust None 5 mg/m3 resp Exposure Limits (STEL) ACGIH OSHA Ingredients (TLV) (PEL) 3. HAZARDS IDENTIFICATION Toxicity: Mild eye irritant. Propylene glycol is a mild skin irritant. Primary Routes of Entry: Eye, skin contact. Signs and symptoms of Exposure: May cause dermatitis on prolonged contact in sensitive individuals. Existing Conditions Aggravated by Exposure: Propylene glycol: dermatitis LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 02 of 05 Product Name: Small Screw Threadlocker 222MS Item No.: 22221 3. HAZARDS IDENTIFICATION (continued) Literature Referenced Carcinogen Ingredients Target Organ and Other Health Effects NTP IARC OSHA Polyglycol dimethacrylate ALG IRR NO NO NO Polyglycol oleate IRR NO NO NO SACCHARIN No Data YES 2B NO CUMENE HYDROPEROXIDE ALG CNS COR IRR MUT NO NO NO Propylene glycol IRR NO NO NO SILICA, AMORPHOUS, FUMED, CRYSTALLINE-FREE NUI NO N/A NO N,N-Dialkyltoluidines No Data NO NO NO TITANIUM DIOXIDE AC4 IRR NUI NO NO NO ------------------------------------------------------------------------------- Abbreviations N/A Not Applicable 2B Possibly carcinogenic to humans AC4 ACGIH-Unclassifiable as human carc. ALG Allergen CNS Central nervous system COR Corrosive IRR Irritant MUT Mutagen NUI Nuisance dust 4. FIRST AID MEASURES Ingestion: Do not induce vomiting. Keep individual calm. Obtain medical attention. Inhalation: Does not apply Skin Contact: Wash with soap and water. Eye Contact: Flush at least 15 minutes with water. Obtain medical attention. 5. FIRE FIGHTING MEASURES Flash Point: More than 200F Method: Tag Closed Cup Recommended Extinguishing Agents: Carbon dioxide, foam, dry chemical Hazardous Products formed by Fire or Thermal Decomp Irritating organic vapors Unusual Fire or Explosion Hazards: None Explosive Limits: (% by volume in air)Lower Propylene glycol: 2.6% (% by volume in air)Upper Propylene glycol: 12.5% LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 03 of 05 Product Name: Small Screw Threadlocker 222MS Item No.: 22221 6. ACCIDENTAL RELEASE MEASURES Steps to be taken in case of spill or leak: Soak up in an inert absorbant. Store in a partly filled, closed container until disposal. 7. HANDLING AND STORAGE Safe Storage: Store below 100F (Contact Loctite Customer Service 1-800-243-4874 for shelf Life information) Handling: Avoid prolonged skin contact. Keep away from eyes. 8. EXPOSURE CONTROLS, PERSONAL PROTECTION Eyes: Safety glasses or goggles. Skin: Neoprene, rubber, or butyl rubber gloves. Ventilation: Does not apply See Section 2 for Exposure Limits. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Purple liquid Odor: Mild Boiling Point: More than 300F pH: Does not apply Solubility in Water: Slight Specific Gravity 1.05 at 80F Volatile Organic Compound (EPA Method 24) 16.0%; 168 grams per liter Vapor Pressure: Less than 5mm at 80F Vapor Density: Not available Evaporation Rate (Ether = 1) Not available 10. STABILITY AND REACTIVITY Stability: Stable Hazardous Polymerization: Will not occur Incompatibility: Strong oxidizers, free radical initiators, inert gases. Conditions to Avoid: Not available Hazardous Decomposition Products (non-thermal): None 11. TOXICOLOGICAL INFORMATION Oral LD50 more than 10000 mg/kg. Dermal LD50 more than 5000 mg.kg. LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 04 of 05 Product Name: Small Screw Threadlocker 222MS Item No.: 22221 12. ECOLOGICAL INFORMATION No data available 13. DISPOSAL CONSIDERATIONS Recommended methods of disposal: Incinerate following EPA and local regulations. EPA Hazardous Waste Number NH - Not a RCRA Hazardous Waste Material 14. TRANSPORTATION INFORMATION DOT (49 CFR 172) Domestic Ground Transport Proper Shipping Name: Unrestricted Hazard Class or Division: Unrestricted Identification Number: None Marine Pollutant: None IATA Proper Shipping Name: Unrestricted Class or Division: Unrestricted UN or ID Number: None 15. REGULATORY INFORMATION CA Proposition 65: This product contains Saccharin. No prop65 hazard warning is necessary if this product is used as reasonably anticipated. 16. OTHER INFORMATION Estimated NFPA(R) Code: Health Hazard: 1 Fire Hazard: 1 Reactivity Hazard: 1 Specific Hazard: Does not apply Estimated HMIS(R) Code: Health Hazard: 1* Flammability Hazard: 1 Reactivity Hazards: 1 Personal Protection: See Section 8. NFPA is a registered trademark of the National Fire Protection Assn. HMIS is a registered trademark of the National Paint and Coatings Assn. Prepared By: Stephen Repetto Title: Research Chemist, Health and Safety LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 05 of 05 Product Name: Small Screw Threadlocker 222MS Item No.: 22221 16. OTHER INFORMATION (continued) Company: Loctite Corporation 1001 Trout Brook Crossing, Rocky HIll CT 06067 (24hr.) Phone: (860) 571-5100 Revision Date: April 16, 1997 Revision: 0028