AOSC 433/633 & CHEM 433 Atmospheric Chemistry & Climate

Instructor: Ross Salawitch

Teaching Assistants: Austin Hope & Tim Vinciguerra

Tues-Thurs, 2:00 to 3:15 pm, CSS 2416

Spring 2015: 3 units

Required Text:

            Chemistry in Context: Applying Chemistry to Society

                        7th edition, American Chemical Society

 

Syllabus

 

ELMS Course Page

 

Supplemental Text:

 

           Global Warming: The Complete Briefing (third edition) by John Houghton

 

The Atmospheric Environment by Michael B. McElroy

 

Beyond Oil and Gas: The Methanol Economy by George A. Olah, Alain Goeppert, and G. K. Surya Prakash

 

Readings from Supplemental Text will be assigned via password protected files posted below.  These files are to be used only for this course.

Notes:

1) We have decided to use the  7th edition of Chemistry in Context rather than the new 8th edition because of student cost (there are hundreds of used copies of the 7th edition available on Amazon for under $20; there is no used copy market for the 8th edition) and Ross actually helped write the 7th edition.  Students have two options: they can rent a copy of the book from Ross for a deposit of $20, fully refundable upon return of the book at the end of the semester.  Or you may purchase a copy of the 7th edition of Chemistry in Context  via Amazon or some other on-line vendor.   Local bookstores are required to have a shelf price of ~$100 for the used version of this book; as a result we have decided to not place book orders with these street and mortar book sellers.  We do not have enough copies of this book for everyone to obtain via rental; these will be made available on a first come, first served basis, with undergraduates given preference over graduate students if we simply can not fill the demand.

 

2) You may find the following web-based resources helpful:

i)  all lectures will be video recorded and posted below

Students are expected to attend lecture!  This resource is provided to assist students with occasional inability to attend class, and to help students review lectures, particularly for exam preparation.  We reserve the right to suspend video recording if lecture attendance becomes markedly lower than prior years.

ii) all emails sent to the entire class will be archived at the following Google Groups page:

http://groups.google.com/group/atmospheric-chemistry-and-climate-2015

We hope all students will read emails as they are sent in the normal manner.  This URL will provide an archive of all email sent to the entire class during the semester.  We have set up this group so that contents are available to everyone (no need to join the group).

 

1. Course Description

2. Course Schedule

3. Grade Policy

4. Admission Tickets

5. In-Class Group Quizzes

6. Additional Readings

7. Collaboration Policy

8. Office Hours

1. Course Description

The effects of human activity on atmospheric composition, focused on global warming, the carbon cycle, air pollution, and the ozone layer. Fundamentals of atmospheric chemistry (spectroscopy, kinetics, isotopic analysis, and biogeochemical cycles) are related to the modern understanding of climate change, air quality, and ozone depletion, based on resources such as satellite missions, field campaigns, and scientific assessments published by international agencies. We also examine how society’s future energy needs could be met in a manner with less impact on atmospheric composition than the present heavy reliance on combustion of fossil fuels.

The course is taught at a level appropriate for upper class undergraduate physical science majors and first year graduate students.

Pre-requisites: CHEM131 or CHEM135 or CHEM146 and MATH 241 or permission of the instructors.

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2. Schedule

Date

Lecture Topic

Required Reading

Admis. Tickets

Lecture Notes

Learning Outcome

Problem Sets*

Additional Readings

01/27

Geological Evolution of Earth's Atmosphere

 NY Times article

(teaching philosophy)

 

Lecture 1

Video

Quiz    

01/29

Overview of Global Warming, Air Quality, & Ozone Depletion

IPCC 2007 FAQ

(questions 1.1, 1.2, 1.3, 2.1, & 3.1)

EPA AQI Brochure

(entire document; only 11 pgs)

WMO 2010 20 QAs

(questions 1, 2, 3, 8, 15 & 18)

Click here for entire WMO 2010 QAs

Click here for entire IPCC 2007 FAQ

AT 2

Lecture 2

Video

 

Quiz

 

 

Kerr, Science, 2007*

Bell et al., EHP, 2006*

Sci American Why is there an ozone hole?  Aug 2007

Naming Convention for CFCs & Halons

02/03

Fundamentals of Earth's Atmosphere

Chemistry in Context: Sec 1.0 to 1.2,

1.5 to 1.8, 1.14, 2.1, 3.6 & 3.7 (~28 pgs)

 

Selected pages, Atmospheric Environment

AT 3*

AT 3#

Lecture 3

Video

Quiz

 

 

 Houghton, Ch 2

02/05

Climates of the Past

Chemistry in Context, Sec 2.2, 3.0, 3.1, 3.2

Houghton, Ch 4

(pgs 64-71)

AT 4

AT 4*

Lecture 4

Video

Quiz

 

Chylek & Lohmann, GRL, 2008*

IPCC 2007 FAQ

(questions 6.1, 6.2)

02/10

Global Carbon Cycle

Chemistry in Context, Sec 3.5, 4.0, 4.1, 6.5

Houghton, Pg 29-42

AT5

Lecture 5

No Video; Panopto was down

Quiz

 

IPCC 2007, Section 7.3.4.1 & Box 7.3

 

Sci American Ocean Acidification

March 2006

02/12

Biogeochemical Cycles of CHand N2O

Chemistry in Context, Sec 3.8 & 6.9

Houghton, Pg 42-44

AT6

Lecture 6

Video

 

Quiz

Problem Set 1  due today

Bruhwiler et al., 2014

Kort et al., 2014

02/17

Stay Warm;

Be Safe !

 

 

 

   
Wed

02/18

Problem Set #1 Review

CSS 3400, 6:30 pm

    Video      
02/19 Radiative Forcing

Chemistry in Context, Sec 2.4, 2.5, 3.3 & 3.4

 AT 7  Lecture 7

Video

Quiz

 

Myhre et al., GRL, 1998

Bera et al., JPC, 2009

02/24

Modeling Earth's Climate: Water Vapor, Aerosol, Cloud, & Albedo Feedbacks

Chemistry in Context, Sec 3.9

Houghton, pg 88-95

Jacobson, Sec 12.4.2 & 12.4.3

 AT 8 

Lecture 8

Video

Quiz

 

Su et al., GRL, 2006

Houghton, Ch 5 (in its entirety)

02/26

 Consequences of Climate Change (brief disc.)

followed by

Review for First Exam

Chemistry in Context,

Sec 3.10

No AT Review A

 

Video

 

  Problem Set 2  due today  
Mon

03/02

Problem Set #2 Review

CSS 2416, 6:30 pm

   

Video

     
03/03

First Exam:

Focus on first 8 Lectures and first 2 Problem Sets (in class, closed book)

           
03/05

OK, we get the message.

Can stop now!

         
Mon

03/09

6:30 pm

Review of First Exam

and

Introduction to Atmospheric Chemistry

Chemistry in Context,

Sec 2.0, 2.3, & 2.6

No AT Student Survey:

Word

   PDF

Lecture 9

Video

Quiz    

03/10

Introduction to Photolysis

Chemistry in Context,

Sec 2.7

Section 2.4 and 2.5 of Warneck, Chemistry of the Natural Atmosphere

(as best you can)

AT 10

 

Lecture 10

Video

Quiz

 

Brasseur and Solomon, pages 40 to 48 (section 2.6), pages 218 and 219 section 4.7.1), and pages 246 and 247 (section 4.7.3)

03/12

Introduction to Chemical Kinetics

Chemistry in Context,

Sec 4.6

Yung & DeMore, Ch 3

AT 11

Lecture 11

Video

Quiz

 

Bimolecular Rate Constant Table, JPL 2010

Brasseur & Solomon, pgs 12 to 40

Spring Break: enjoy !

03/24

Pollution of Earth's Troposphere:

   Surface Ozone

Chemistry in Context, Sec 1.3, 1.4, 1.9, 1.10, 1.11, 1.12, 1.15, 4.3, 6.10, 6.14

AT 12 Lecture 12

 

Video

Quiz

 

Chemistry in Context, Sec 4.7

03/26

Pollution of Earth's Troposphere:

   Acid Rain & Aerosols

Chemistry in Context, Sec 6.0, 6.1, 6.2, 6.3, 6.6, 6.7, 6.11, 6.12, 6.13

AT 13 Lecture 13

 

Video

Quiz

  Chemistry in Context, Sec 6.4

03/31

Pollution of Earth's Stratosphere:

   Mid-Latitude Ozone Depletion

Chemistry in Context, Sec 2.8, 2.9

WMO 2010 20 QAs

(questions 4, 6 to 9, 13 to 17)

AT 14

Lecture 14

Video

 Quiz

Problem Set 3 due today

McElroy, Chapter 13

(pgs 175-178 & 183-187)*

 

McElroy,

Chapter 14*

04/02

Pollution of Earth's Stratosphere:

   Polar Ozone Depletion

Chemistry in Context, Sec 2.10, 2.11, 2.12 & 2.13

WMO 2010 20 QAs

(quest. 9-12)

AT 15

Lecture 15

Video

Quiz  

McElroy, Chapter 15*

Rex et al., 2006

Manney et al., 2011

Mon

04/06

Problem Set #3 Review

CSS 2416, 6:30 pm

   

Video

     

04/07

Pollution of Earth's Stratosphere:

   Ozone Recovery and Chemistry/Climate   

   Interactions

WMO 2006 20 QAs

(quest. 19 & 20)

AT 16

Lecture 16

Video

Quiz  

Oman et al., 2010

Revell et al., 2012*

04/09 Review Discussion for Second Exam   No AT Review B

Video

No Quiz Problem Set 4 due today  
Mon

04/13

Problem Set #4 Review

CSS 2416, 6:30 pm

    Video      

04/14

Second Exam:

Focus on Lectures 9 to 16 & Problem Sets 3 and 4 (in class, closed book)

 

 

 

     

04/16

Review of Second Exam as well as

World Energy Needs and Fossil Fuel Reserves

Chemistry in Context, Sec 4.2, 4.4 & 4.5

World Energy Outlook Summary for Policy Makers, 2014

No AT;  please complete readings

Lecture 17

Video

Quiz  

Peak Oil Wikipedia

04/21

The Kyoto Protocol and the Science of CO2 Stabilization

Chemistry in Context, Sec 3.11, 4.8, 4.11 & 4.12

Houghton, Ch 10

EPA GHG Endangerment Finding

AT 18

Lecture 18

Video

Quiz  

Pacala & Socolow 2004

Raupach et al. 2007

IPCC 2007 FAQ (question 10.3)

04/23

Renewable Energy I: Solar, Geothermal, Hydro, & Wind

Chemistry in Context,

Sec 8.7, 8.8 & 8.9

Olah, Sec 8.1 to 8.5

AT 19 

Lecture 19

Video

 

Quiz  

Wind: NREL

Hydro: Grand Coulee Dam

 Solar: Univ Park Community Solar

04/28

Renewable Energy II: Biofuels, Ethanol, Methanol, and Algae

Chemistry in Context, Sec 4.9, 4.10

 

Olah, Sec 8.6

AT 20 

Lecture20

Video

Quiz  

McElroy, The Ethanol Illusion

Wigmosta et al., WRR, 2011

04/30 Fracking Fracking Debate: Please read main page, plus at least one "no" & one "yes" argument

Howarth, 2014

(please read section entitled "How Much Methane is Emitted by Natural Gas Systems)

AT 21 

Lecture 21

Video

Quiz Problem Set 5 due today

Howarth, 2014*

(633 students please read rest of this paper)

Allen et al., 2013

Schneising et al., 2014

05/05

Nuclear Energy & The Hydrogen Economy

Chemistry in Context, Chapter 7 (except for Secs 7.2 & 7.6)

Olah, Sec 9.3, 9.4 & 9.5

AT 22  √

Lecture 22

Video

Quiz  

Chemistry in Context,

Sec 7.2 & 7.6

 

Olah, Sec 8.8 (Intro), 8.8.1 & 8.8.2

Wed

05/06

Problem Set #5 Review

CSS 2416, 6:30 pm

   

Video

     
05/07 Geo-engineering of Climate

Crutzen GeoEng Essay

IEEE GeoEng Overview

AT 23

Lecture 23

Video

Quiz

Problem Set 6 due today

Assigned only to 433 students who are not doing a project

Tilmes et al., 2008

Canty et al., 2013

GeoTimes GeoEng Debate

Mon

05/11

633 Project Presentations

CSS 2416, 6:30 pm

   

Video

  Paper due for students enrolled in 633  
05/12 Class Review: Preparation for Final Exam   No AT Review C

Video

     

05/18

Final Exam

CSS 2416

10:30 am  12:30 pm

           

  Problem sets due on the date listed

* Reading strongly suggested for students enrolled in AOSC 633

x Denotes hyperlink, hard-wired ahead of time to make the webmaster's life easier, is not yet working

  Denotes active hyperlink

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3. Grade Policy

The overall grades will be based on problems sets (25%), admission tickets (10%), in-class group quizzes (5%), two in-class exams (40%), and the final exam (20%). In addition, students enrolled in AOSC 633 are required to write a research paper that is 6 to 8 pages long (single spaced) on a topic of their choosing related to the material covered in class. These students will make a brief oral presentation of their research paper during either a special evening session; the grade on the paper/presentation will be factored into their overall grade at a proportion equal to the weight of each exam. Students enrolled in 633 will also have an extra question on each problem set.

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4. Admission Tickets

To encourage completion of the reading assignments prior to class, there is an admission ticket due at the start of each class (with the exception of the first lecture). The admission ticket is a short question (or set of questions) drawn from the readings. Each ticket will be graded in a prompt manner and typically returned at the start of the next class. The lowest three scores will be dropped, and a final overall admission ticket grade will be determined, based on overall percentage of available points achieved. This allows for uniform grading of admission tickets with a variety of assigned points. The overall admission ticket grade counts 10% towards the final course grade.

In many cases, the answer(s) to the admission ticket question(s) will be worked into the lecture. Hence, the requirement that admission ticket solutions be turned in at the start of lecture. If you can not make a lecture, you are welcome to email us your solution prior to class or have a classmate turn in your solution. Late submissions of admission ticket solutions are generally not accepted. Since the three lowest scores are dropped and admission tickets constitute only 10% of the overall grade, we are rather strict about not accepting late admission ticket solutions. Again, these questions are designed to motivate completion of the assigned reading prior to lecture, which is an important component of learning.

Admission tickets will be posted on this website at least 24 hours prior to the start of each lecture. If an admission ticket for a particular lecture is not posted by 2 pm the day prior to a particular lecture, there will be no admission ticket for that class. Also, if an item other than an admission ticket link appears in the admission ticket column for a particular lecture (i.e., lectures 1, 9, and 14), there will no admission ticket for that class meeting.

We may administer an occasional, in class ''pop quiz''. This will be done if it is apparent that a majority of students are not completing the readings prior to class (e.g., if the admission ticket answers seem, in aggregate, to be based on Google searches of key phrases rather than reading of the assigned material). If one or more ''pop quiz'' is given, the results will be factored into the ''admission ticket'' portion of the grade.

Please remember to hit the ''refresh'' button to see the latest version of this website each time you visit, as we intend to update the website file frequently during the course (if the symbol x is changed to the symbol , this may not be apparent unless the page is refreshed).

5. In-Class Group Quizzes

In-class group quizzes will be conducted on a trial basis for Spring 2015. During many lectures, we will break, organize into groups led by a student enrolled in 633, then each will work together for about 5 minutes on answering a question related to that day's lecture. The written answer will be turned in, containing the name of everyone in the group. A single grade will of course be assigned, shared by all members of the group. It is hoped that the composition of the groups will vary from lecture to lecture ... if necessary we will work with the class on a means of achieving this goal. If a student has an excused absence from class, they will receive the mean grade of the the group quizzes for that lecture (i.e., absence will neither help nor hinder your overall grade). Unexcused absence will receive a zero. The lowest 2 in-class grades will be dropped, to assure a level of fairness for students who happen to miss a lecture or two due to an unexcused absence.

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6. Additional Readings

Additional readings are provided for many lectures. This material is provided to allow interested students to read further about a particular topic. The material in these additional readings will not form the sole basis of any exam question, nor will this material be of purposeful advantage for the successful completion of the problem sets. Learning the course material will be enhanced for those with time to complete the additional readings.

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7. Collaboration Policy

For completion of the Admission Tickets and Problem Sets, you may consult any text or website you desire. While we encourage reliance on the assigned reading and discourage use of search engines for the completion of the Admission Tickets, we also understand the utility of search engines and understand they provide a useful resource. Regardless, the material you turn in for Admission Tickets and Problem Sets should reflect your understanding of the material and only your work. We encourage discussion among classmates of general course concepts, but details of how to answer particular admission ticket problem set questions should not be discussed with classmates. Rather, you are strongly encouraged to interact with the course instructor for answering Admission Ticket or Problem Set questions. After material has been returned, you are welcome to discuss solutions with other students. Also, it is fine to prepare for the examinations by discussing class material with other students. We take care to change questions every year, in part to keep material fresh but also to discourage any benefit to students who have access to material passed down from prior years in student files.

Simply put: it is not permissible to copy solutions for Admission Tickets and Problem Sets from other students or from files for this class maintained by prior students. Exam questions for this class will not be a repeat of questions from prior exams.

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8. Office Hours

Office Hours:

Ross (CSS 2403): Mon 2 to 3 pm & by appointment

Austin (CSS 4365): Mon 3 to 4 pm, Wed 2 to 3 pm & by appointment

Tim (CHE Bldg 090, 1305): Wed 3 to 4 pm & by appointment

 

Phone:

Ross: 5-5396

After class often works although the AOSC seminar is held Thurs at 3:30 pm

 

Just prior to class is generally not a good time for interacting with Ross, because he is typically focused on preparing for that day's lecture.

We strive to be accessible throughout the semester. Please either drop by or contact us via email to set up a time to meet.

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Website last updated on Friday, 15 May 2015